Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis

被引：10

作者：

Zhang, Guodong ^{[1
,2
]}

Lang, Rui ^{[1
,2
]}

Wang, Wenlong ^{[1
]}

Lv, Hui ^{[1
]}

Zhao, Liyuan ^{[1
]}

Xia, Chungu ^{[1
]}

Li, Fuwei ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 05期

基金：

中国国家自然科学基金;

关键词：

carbenes; copper; homogeneous catalysis; ligand design; sustainable chemistry; SUZUKI-MIYAURA REACTION; AEROBIC OXIDATION; RECYCLABLE CATALYSTS; WATER; ALCOHOLS; ALDEHYDES; LIGAND; FUNCTIONALITY; AMIDINE;

D O I：

10.1002/adsc.201401140

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis of a light-responsive N-heterocyclic carbene copper(I) complex by introducing a nitrobenzospiropyran unit into the carbene ligand was developed. The solubility of this complex was controlled through reversible conversion between its netural and ionic states using ultraviolet light irradiation. Taking advantage of such a light-sensitive property facilitated its recovery and reuse in copper(I)-catalyzed homogeneous oxidation and "click" reactions.

引用

页码：917 / 922

页数：6

共 50 条

[41] Influence of a Very Bulky N-Heterocyclic Carbene in Gold-Mediated Catalysis [J].

Gomez-Suarez, Adrian ;

Ramon, Ruben S. ;

Songis, Olivier ;

Slawin, Alexandra M. Z. ;

Cazin, Catherine S. J. ;

Nolan, Steven P. .

ORGANOMETALLICS, 2011, 30 (20) :5463-5470

[42] Copper N-Heterocyclic Carbene: A Catalyst for Aerobic Oxidation or Reduction Reactions [J].

Zhan, Le-Wu ;

Han, Lei ;

Xing, Ping ;

Jiang, Biao .

ORGANIC LETTERS, 2015, 17 (24) :5990-5993

[43] Hybrid Surfactants with N-Heterocyclic Carbene Heads as a Multifunctional Platform for Interfacial Catalysis [J].

Donner, Adrian ;

Hagedorn, Kay ;

Mattes, Lorenz ;

Drechsler, Markus ;

Polarz, Sebastian .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (72) :18129-18133

[44] The Developing Concept of Bifunctional Catalysis with Transition Metal N-Heterocyclic Carbene Complexes [J].

Ramasamy, Balasubramaniyam ;

Ghosh, Prasenjit .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (10) :1448-1465

[45] Enantioselective Synthesis of Tertiary Propargylic Alcohols under N-Heterocyclic Carbene Catalysis [J].

Sanchez-Diez, Eduardo ;

Fernandez, Maitane ;

Uria, Uxue ;

Reyes, Efraim ;

Carrillo, Luisa ;

Vicario, Jose L. .

CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (23) :8384-8388

[46] Induced-Fit Chiral N-Heterocyclic Carbene Ligands for Asymmetric Catalysis [J].

Wang, Zi-Chao ;

Shi, Shi-Liang .

ACCOUNTS OF CHEMICAL RESEARCH, 2025, 58 (13) :2157-2177

[47] N-heterocyclic carbene copper(I) complex-catalyzed direct C-H thiolation of benzothiazoles [J].

Inomata, Hiroshi ;

Toh, Ayumi ;

Mitsui, Takashi ;

Fukuzawa, Shin-ichi .

TETRAHEDRON LETTERS, 2013, 54 (35) :4729-4731

[48] Copper(I)/N-Heterocyclic Carbene (NHC)-Catalyzed Addition of Terminal Alkynes to Trifluoromethyl Ketones for Use in Continuous Reactors [J].

Correia, Camille A. ;

McQuade, D. Tyler ;

Seeberger, Peter H. .

ADVANCED SYNTHESIS & CATALYSIS, 2013, 355 (18) :3517-3521

[49] Reductive Synthesis of Alcohols from Carboxylic Acids and Esters Catalyzed by a Copper N-heterocyclic Carbene Complex [J].

Zhou, Hui ;

Wei, Nana ;

Ren, Zhiqiang ;

Ma, Haojie ;

Zhang, Yuqi ;

Han, Bo .

CHINESE JOURNAL OF CHEMISTRY, 2025, 43 (01) :73-78

[50] Recent Advances in Organic Synthesis Using Light-Mediated N-Heterocyclic Carbene Catalysis [J].

Marzo, Leyre .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2021, 2021 (33) :4603-4610

← 1 2 3 4 5 →