Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis

被引：10
|
作者：
Zhang, Guodong [1 ,2 ]
Lang, Rui [1 ,2 ]
Wang, Wenlong [1 ]
Lv, Hui [1 ]
Zhao, Liyuan [1 ]
Xia, Chungu [1 ]
Li, Fuwei [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2015年 / 357卷 / 05期
基金：
中国国家自然科学基金;
关键词：
carbenes; copper; homogeneous catalysis; ligand design; sustainable chemistry; SUZUKI-MIYAURA REACTION; AEROBIC OXIDATION; RECYCLABLE CATALYSTS; WATER; ALCOHOLS; ALDEHYDES; LIGAND; FUNCTIONALITY; AMIDINE;
D O I：
10.1002/adsc.201401140
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The synthesis of a light-responsive N-heterocyclic carbene copper(I) complex by introducing a nitrobenzospiropyran unit into the carbene ligand was developed. The solubility of this complex was controlled through reversible conversion between its netural and ionic states using ultraviolet light irradiation. Taking advantage of such a light-sensitive property facilitated its recovery and reuse in copper(I)-catalyzed homogeneous oxidation and "click" reactions.
引用
收藏
页码：917 / 922
页数：6
相关论文
共 50 条
  • [31] Synthesis and structures of cyclopentadienyl N-heterocyclic carbene copper(I) complexes
    Ren, Hongping
    Zhao, Xi
    Xu, Shansheng
    Song, Haibin
    Wang, Baiquan
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (19) : 4109 - 4113
  • [32] N-heterocyclic carbenes in homogeneous catalysis.
    Nolan, SP
    Grasa, GA
    Viciu, MS
    Kissling, RM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U629 - U629
  • [33] Kinetic Resolutions Enabled by N-Heterocyclic Carbene Catalysis
    Yang, Shuang
    Fang, Xinqiang
    CURRENT ORGANIC SYNTHESIS, 2017, 14 (05) : 654 - 664
  • [34] Water in N-Heterocyclic Carbene-Assisted Catalysis
    Levin, Efrat
    Ivry, Elisa
    Diesendruck, Charles E.
    Lemcoff, N. Gabriel
    CHEMICAL REVIEWS, 2015, 115 (11) : 4607 - 4692
  • [35] N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis
    Kazunori Nagao
    Hirohisa Ohmiya
    Topics in Current Chemistry, 2019, 377
  • [36] A cooperative N-heterocyclic carbene/palladium catalysis system
    Liu, Kun
    Hovey, M. Todd
    Scheidt, Karl A.
    CHEMICAL SCIENCE, 2014, 5 (10) : 4026 - 4031
  • [37] N-Heterocyclic Carbene Catalysis under Oxidizing Conditions
    Dzieszkowski, Krzysztof
    Rafinski, Zbigniew
    CATALYSTS, 2018, 8 (11)
  • [38] N-Heterocyclic Carbene (NHC)/Metal Cooperative Catalysis
    Nagao, Kazunori
    Ohmiya, Hirohisa
    TOPICS IN CURRENT CHEMISTRY, 2019, 377 (06)
  • [39] β-Sulfonylation of α-bromoenals enabled by N-heterocyclic carbene catalysis
    Jin, Shiyi
    Fang, Shuaishuai
    Ma, Rui
    Liang, Zheng
    Xu, Ye
    Lu, Tao
    Du, Ding
    ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (19): : 3392 - 3396
  • [40] Discovering New Reactions with N-Heterocyclic Carbene Catalysis
    Phillips, Eric M.
    Chan, Audrey
    Scheidt, Karl A.
    ALDRICHIMICA ACTA, 2009, 42 (03) : 55 - 66
12345