New stable catalysts of the Pauson-Khand annelation

被引:34
作者
Comely, AC
Gibson, SE
Stevenazzi, A
Hales, NJ
机构
[1] Kings Coll London, Dept Chem, London WC2R 2LS, England
[2] AstraZeneca UK Ltd, Macclesfield SK10 4TG, Cheshire, England
关键词
D O I
10.1016/S0040-4039(00)02204-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A range of phosphine- and phosphite-substituted carbonylcobalt(0) complexes have been synthesised and screened as catalysts of the Pauson Khand annelation. The readily prepared stable solid, heptacarbonyl(triphenylphosphine)dicobalt(0) 1. performed well (78% yield) in a benchmark annelation reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1183 / 1185
页数:3
相关论文
共 14 条
[1]   REACTIONS OF TRISULFONATED TRIPHENYLPHOSPHINE, TPPTS, WITH COBALT CARBONYLS IN WATER [J].
BARTIK, T ;
BARTIK, B ;
HANSON, BE ;
WHITMIRE, KH ;
GUO, I .
INORGANIC CHEMISTRY, 1993, 32 (25) :5833-5837
[2]   Thermal promotion of the cobalt catalyzed intramolecular Pauson-Khand reaction - An alternative experimental protocol for cyclopentenone synthesis [J].
Belanger, DB ;
O'Mahony, DJR ;
Livinghouse, T .
TETRAHEDRON LETTERS, 1998, 39 (42) :7637-7640
[3]   Hexacarbonyldicobalt-alkyne complexes as convenient Co2(CO)8 surrogates in the catalytic Pauson-Khand reaction [J].
Belanger, DB ;
Livinghouse, T .
TETRAHEDRON LETTERS, 1998, 39 (42) :7641-7644
[4]   THE EFFECT OF ULTRASOUND AND OF PHOSPHINE AND PHOSPHINE-OXIDES ON THE KHAND REACTION [J].
BILLINGTON, DC ;
HELPS, IM ;
PAUSON, PL ;
THOMSON, W ;
WILLISON, D .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 354 (02) :233-242
[5]   Polymer-supported cobalt carbonyl complexes as novel solid-phase catalysts of the Pauson-Khand reaction [J].
Comely, AC ;
Gibson, SE ;
Hales, NJ .
CHEMICAL COMMUNICATIONS, 2000, (04) :305-306
[6]   The aryl effect in disubstituted dimanganese and dicobalt carbonyls [J].
Farrar, DH ;
Hao, JB ;
Poe, AJ ;
Stromnova, TA .
ORGANOMETALLICS, 1997, 16 (13) :2827-2832
[7]   CATALYTIC VERSION OF THE INTRAMOLECULAR PAUSON-KHAND REACTION [J].
JEONG, N ;
HWANG, SH ;
LEE, YS ;
CHUNG, YK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (07) :3159-3160
[8]  
KHAND IU, 1971, J CHEM SOC CHEM COMM, P36
[9]   ORGANOCOBALT COMPLEXES .2. REACTION OF ACETYLENEHEXACARBONYLDICOBALT COMPLEXES, (R1C2R2)CO2(CO)6, WITH NORBORNENE AND ITS DERIVATIVES [J].
KHAND, IU ;
KNOX, GR ;
PAUSON, PL ;
WATTS, WE ;
FOREMAN, MI .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (09) :977-981
[10]   Modification and limitations of the Livinghouse catalytic Pauson-Khand reaction [J].
Krafft, ME ;
Bonaga, LVR ;
Hirosawa, C .
TETRAHEDRON LETTERS, 1999, 40 (52) :9171-9175