Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

被引：35

作者：

Huang, Jianmei ^{[1
,2
]}

Tan, Yingbin ^{[3
]}

Su, Jiahao ^{[3
]}

Gu, Qinfen ^{[4
]}

Cerny, Radovan ^{[5
]}

Ouyang, Liuzhang ^{[1
,2
]}

Sun, Dalin ^{[3
]}

Yu, Xuebin ^{[3
]}

Zhu, Min ^{[1
,2
]}

机构：

[1] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China

[2] S China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China

[3] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China

[4] Australian Synchrotron, Clayton, Vic 3168, Australia

[5] Univ Geneva, DQMP, Lab Cristallog, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 14期

基金：

中国国家自然科学基金;

关键词：

HYDROGEN-STORAGE; METAL BOROHYDRIDES; RECENT PROGRESS; DECOMPOSITION; STABILITY; HYDRIDES; COMPLEX;

D O I：

10.1039/c4cc09317h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new metal borohydride ammoniate (MBA), Zr(BH4)(4)center dot 8NH(3), was synthesized via ammoniation of the Zr(BH4)(4) crystal. Zr(BH4)(4)center dot 8NH(3) has a distinctive structure and the highest coordination number of NH3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 degrees C, enabling it a potential hydrogen storage material.

引用

页码：2794 / 2797

页数：4

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