Chain and rhomboidal "box"-like polymeric metal complexes of N,N′-1,2-ethylenebis(pyridin-2-thione)

被引：5

作者：

Atherton, Z ^{[1
]}

Goodgame, DML ^{[1
]}

Katahira, DA ^{[1
]}

Menzer, S ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

POLYHEDRON | 1998年 / 17卷 / 13-14期

关键词：

X-ray structures; polymeric complexes; bis(pyridine-2-thione) ligand;

D O I：

10.1016/S0277-5387(98)00029-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations are reported of a range of complexes of Fe-II, Co-II, Ni-II, Cu-I, Ag-I; Zn and Cd with N,N'-1,2-ethylenebis(pyridin-2-thione) (EBPYT) together with relevant spectroscopic data. The compounds Co(EBPYT)Br-2 (1) and [Ni(EBPYT)(3)](ClO4)(2) . 2MeOH . MeNO2 (2) have been studied by X-ray crystallography. Compound 1 has a chain structure in which tetrahedrally coordinated cobalt centres are linked by bridging EBPYT ligands. In compound 2 octahedrally coordinated "NIS6" centres are connected by EBPYT bridges so as to form a polymeric three-dimensional array of rhomboidal "boxes". (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2257 / 2265

页数：9

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