Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols

被引：91

作者：

Ding, Qiuping ^{[1
,2
]}

Cao, Banpeng ^{[1
]}

Yuan, Jianjun ^{[1
]}

Liu, Xianjin ^{[1
]}

Peng, Yiyuan ^{[1
,2
]}

机构：

[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China

[2] Key Lab Green Chem Jiangxi Prov, Nanchang 330022, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 03期

关键词：

ALPHA-DIAZOCARBONYL COMPOUNDS; BOND FORMATION; EFFICIENT SYNTHESIS; ADDITION-REACTIONS; ARYL HALIDES; H BONDS; SULFIDES; SELENIDES; CATALYST; ALKYL;

D O I：

10.1039/c0ob00639d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A metal-free procedure for the synthesis of thioethers is described via the base-promoted reductive coupling of tosylhydrazones with thiols through an insertion of a carbene into the S-H bond.

引用

页码：748 / 751

页数：4