Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols

被引：91
|
作者：
Ding, Qiuping [1 ,2 ]
Cao, Banpeng [1 ]
Yuan, Jianjun [1 ]
Liu, Xianjin [1 ]
Peng, Yiyuan [1 ,2 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China
[2] Key Lab Green Chem Jiangxi Prov, Nanchang 330022, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 03期
关键词：
ALPHA-DIAZOCARBONYL COMPOUNDS; BOND FORMATION; EFFICIENT SYNTHESIS; ADDITION-REACTIONS; ARYL HALIDES; H BONDS; SULFIDES; SELENIDES; CATALYST; ALKYL;
D O I：
10.1039/c0ob00639d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A metal-free procedure for the synthesis of thioethers is described via the base-promoted reductive coupling of tosylhydrazones with thiols through an insertion of a carbene into the S-H bond.
引用
收藏
页码：748 / 751
页数：4
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