KOH based selective wet chemical etching of AlN, AlxGa1-xN, and GaN crystals: A way towards substrate removal in deep ultraviolet-light emitting diode

被引:82
作者
Guo, W. [1 ]
Kirste, R. [1 ]
Bryan, I. [1 ]
Bryan, Z. [1 ]
Hussey, L. [1 ]
Reddy, P. [1 ]
Tweedie, J. [2 ]
Collazo, R. [1 ]
Sitar, Z. [1 ]
机构
[1] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA
[2] Adroit Mat, Apex, NC 27539 USA
基金
美国国家科学基金会;
关键词
GROWTH; POLAR;
D O I
10.1063/1.4913705
中图分类号
O59 [应用物理学];
学科分类号
摘要
A controllable and smooth potassium hydroxide-based wet etching technique was developed for the AlGaN system. High selectivity between AlN and AlxGa1-xN (up to 12 x) was found to be critical in achieving effective substrate thinning or removal for AlGaN-based deep ultraviolet light emitting diodes, thus increasing light extraction efficiency. The mechanism of high selectivity of AlGaN as a function of Al composition can be explained as related to the formation and dissolution of oxide/hydroxide on top of N-polar surface. Cross-sectional transmission electron microscopic analysis served as ultimate proof that these hillocks were not related to underlying threading dislocations. (C) 2015 AIP Publishing LLC.
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页数:4
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共 24 条
[1]   Wet KOH etching of freestanding AlN single crystals [J].
Bickermann, M. ;
Schmidt, S. ;
Epelbaum, B. M. ;
Heimann, P. ;
Nagata, S. ;
Winnacker, A. .
JOURNAL OF CRYSTAL GROWTH, 2007, 300 (02) :299-307
[2]  
Collazo R., 2011, CLEO SCI INNOVATIONS
[3]   On the origin of the 265 nm absorption band in AlN bulk crystals [J].
Collazo, Ramon ;
Xie, Jinqiao ;
Gaddy, Benjamin E. ;
Bryan, Zachary ;
Kirste, Ronny ;
Hoffmann, Marc ;
Dalmau, Rafael ;
Moody, Baxter ;
Kumagai, Yoshinao ;
Nagashima, Toru ;
Kubota, Yuki ;
Kinoshita, Toru ;
Koukitu, Akinori ;
Irving, Douglas L. ;
Sitar, Zlatko .
APPLIED PHYSICS LETTERS, 2012, 100 (19)
[4]   Growth and Characterization of AlN and AlGaN Epitaxial Films on AlN Single Crystal Substrates [J].
Dalmau, R. ;
Moody, B. ;
Schlesser, R. ;
Mita, S. ;
Xie, J. ;
Feneberg, M. ;
Neuschl, B. ;
Thonke, K. ;
Collazo, R. ;
Rice, A. ;
Tweedie, J. ;
Sitar, Z. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (05) :H530-H535
[5]   Vacancy compensation and related donor-acceptor pair recombination in bulk AlN [J].
Gaddy, Benjamin E. ;
Bryan, Zachary ;
Bryan, Isaac ;
Kirste, Ronny ;
Xie, Jinqiao ;
Dalmau, Rafael ;
Moody, Baxter ;
Kumagai, Yoshinao ;
Nagashima, Toru ;
Kubota, Yuki ;
Kinoshita, Toru ;
Koukitu, Akinori ;
Sitar, Zlatko ;
Collazo, Ramon ;
Irving, Douglas L. .
APPLIED PHYSICS LETTERS, 2013, 103 (16)
[6]   Comparative study of etching high crystalline quality AlN and GaN [J].
Guo, W. ;
Xie, J. ;
Akouala, C. ;
Mita, S. ;
Rice, A. ;
Tweedie, J. ;
Bryan, I. ;
Collazo, R. ;
Sitar, Z. .
JOURNAL OF CRYSTAL GROWTH, 2013, 366 :20-25
[7]   Stimulated emission and optical gain in AlGaN heterostructures grown on bulk AlN substrates [J].
Guo, Wei ;
Bryan, Zachary ;
Xie, Jinqiao ;
Kirste, Ronny ;
Mita, Seiji ;
Bryan, Isaac ;
Hussey, Lindsay ;
Bobea, Milena ;
Haidet, Brian ;
Gerhold, Michael ;
Collazo, Ramon ;
Sitar, Zlatko .
JOURNAL OF APPLIED PHYSICS, 2014, 115 (10)
[8]   Properties of AlN based lateral polarity structures [J].
Kirste, Ronny ;
Mita, Seiji ;
Hoffmann, Marc P. ;
Hussey, Lindsay ;
Guo, Wei ;
Bryan, Isaac ;
Bryan, Zachary ;
Tweedie, James ;
Gerhold, Michael ;
Hoffmann, Axel ;
Collazo, Ramon ;
Sitar, Zlatko .
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 11, NO 2, 2014, 11 (02) :261-264
[9]   Polarity control and growth of lateral polarity structures in AlN [J].
Kirste, Ronny ;
Mita, Seiji ;
Hussey, Lindsay ;
Hoffmann, Marc P. ;
Guo, Wei ;
Bryan, Isaac ;
Bryan, Zachary ;
Tweedie, James ;
Xie, Jinqiao ;
Gerhold, Michael ;
Collazo, Ramon ;
Sitar, Zlatko .
APPLIED PHYSICS LETTERS, 2013, 102 (18)
[10]   Ultraviolet semiconductor laser diodes on bulk AlN [J].
Kneissl, Michael ;
Yang, Zhihong ;
Teepe, Mark ;
Knollenberg, Cliff ;
Schmidt, Oliver ;
Kiesel, Peter ;
Johnson, Noble M. ;
Schujman, Sandra ;
Schowalter, Leo J. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (12)