Fabrication of Sb2S3 thin films by sputtering and post-annealing for solar cells

被引:83
作者
Gao, Chunhui [1 ]
Huang, Jialiang [2 ]
Li, Huangxu [1 ]
Sun, Kaiwen [2 ]
Lai, Yanqing [1 ]
Jia, Ming [1 ]
Jiang, Liangxing [1 ]
Liu, Fangyang [1 ,2 ]
机构
[1] Cent S Univ, Sch Met & Environm, Changsha 410083, Peoples R China
[2] Univ New South Wales, Sch Photovolta & Renewable Energy Engn, Sydney, NSW 2052, Australia
关键词
Sb2S3 thin films; Post-annealing conditions; Element distribution; Photoelectric conversion efficiency; IN-SITU GROWTH; OPTICAL-PROPERTIES; ELECTRONIC-STRUCTURE; ABSORBER; EFFICIENCY; PHOTOVOLTAICS; NANOCRYSTALS; TEMPERATURE; DEPOSITION; CUSBS2;
D O I
10.1016/j.ceramint.2018.10.155
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The semiconductor antimony sulfide (Sb2S3) is a potential absorber materials for the top sub-cell of Si-based tandem solar cells because of its appropriate band-gap, simple binary composition, nontoxic elements, and long-term stability. In this study, polycrystalline Sb2S3 films were fabricated by post-annealing of radio frequency (RF) magnetron sputtered precursors using an Sb2S3 target. The effects of the post-annealing temperature and atmosphere on Sb2S3 film properties and device performances were investigated. A high-performance device having a 2.41% power conversion efficiency was obtained by making use of a uniform Sb2S3 absorber layer. This preliminary experimental study shows that Sb2S3 thin films could be used as top sub-cell absorber materials for third-generation high efficiency, stable, and environmentally friendly Sb2S3/Si tandem solar cells.
引用
收藏
页码:3044 / 3051
页数:8
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