Ferrate(VI) oxidation of aqueous cyanide

被引：109
作者：
Sharma, VK [1 ]
Rivera, W [1 ]
Smith, JO [1 ]
O'Brien, B [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, Corpus Christi, TX 78412 USA
来源：
ENVIRONMENTAL SCIENCE & TECHNOLOGY | 1998年 / 32卷 / 17期
关键词：
D O I：
10.1021/es970820k
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The rates of oxidation of cyanide with Fe(VI) were measured as a function of pH (8.0-12) and temperature (15-30 degrees C). The reaction was found to be first order for each reactant. The rates decrease with increasing pH. The energy of activation was found to be 38.9 +/- 1.0 kJ mol(-1) at pH 9.0. The removal of cyanide by oxidation with Fe(VI) was studied at pH 7.5, 9.0, and 12.0. Fe(VI) removal efficiency was greater at pH 9.0 than at pH 7.5 and 12.0. At pH 9.0, Fe(VI) molar consumption was nearly equal to that of oxidized cyanide. Cyanate and nitrite ions were identified as the products of the reaction at pH 7.5. The experiments indicated 1:1 stoichiometric conversion of cyanide to nitrite ion at pH 9.0 and 12.0. Experiments were conducted to test the Fe(VI) removal efficiency of cyanide in electroplating rinsewater. The results indicate that Fe(VI) has the potential to serve as a reliable and safe oxidative treatment for removing cyanide in wastewater effluent.
引用
收藏
页码：2608 / 2613
页数：6
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