Photocatalytic degradation of C.I. Basic Violet 10 using TiO2 catalysts supported by Y zeolite:: An investigation of the effects of operational parameters

被引:222
作者
Wang, Cheng-Cai [1 ]
Lee, Chung-Kung
Lyu, Meng-Du
Juang, Lain-Chuen
机构
[1] Vanung Univ, Green Environm R&D Ctr, Tao Yuan 32061, Taiwan
[2] Vanung Univ, Dept Environm Engn, Tao Yuan 32061, Taiwan
关键词
TiO2; Y zeolite; photocatalytic degradation; cationic dye; operational parameters; catalyst;
D O I
10.1016/j.dyepig.2007.02.004
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The physical and chemical states of zeolite-supported TiO2 were evaluated via powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) and nitrogen adsorption-desorption isotherms. The effects of operational parameters, including TiO2 content, calcination temperature, pH, initial dye concentration, as well as catalyst dosage, on photocatalytic degradation performance were examined. The photocatalytic reaction followed first-order kinetics for all catalysts; optimum photodegradation efficiency was found to result from the use of a high TiO2 concentration (20% TiO2), a calcination temperature of 600 degrees C, alkaline pH (9-10) and a catalyst dosage of 5333 ppm. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:817 / 824
页数:8
相关论文
共 33 条
[31]   Titanium dioxide/adsorbent hybrid photocatalysts for photodestruction of organic substances of dilute concentrations [J].
Yoneyama, H ;
Torimoto, T .
CATALYSIS TODAY, 2000, 58 (2-3) :133-140
[32]   Photocatalytic degradation of AZO dyes by supported TiO2+UVin aqueous solution [J].
Zhu, CM ;
Wang, LY ;
Kong, LR ;
Yang, X ;
Wang, LS ;
Zheng, SJ ;
Chen, FL ;
Feng, MZ ;
Zong, H .
CHEMOSPHERE, 2000, 41 (03) :303-309
[33]   The pH influence on photocatalytic decomposition of organic dyes over A11 and P25 titanium dioxide [J].
Zielinska, B ;
Grzechulska, J ;
Kalenczuk, RJ ;
Morawski, AW .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 45 (04) :293-300