Photocatalytic degradation of C.I. Basic Violet 10 using TiO2 catalysts supported by Y zeolite:: An investigation of the effects of operational parameters

被引：220
作者：
Wang, Cheng-Cai [1 ]
Lee, Chung-Kung
Lyu, Meng-Du
Juang, Lain-Chuen
机构：
[1] Vanung Univ, Green Environm R&D Ctr, Tao Yuan 32061, Taiwan
[2] Vanung Univ, Dept Environm Engn, Tao Yuan 32061, Taiwan
来源：
DYES AND PIGMENTS | 2008年 / 76卷 / 03期
关键词：
TiO2; Y zeolite; photocatalytic degradation; cationic dye; operational parameters; catalyst;
D O I：
10.1016/j.dyepig.2007.02.004
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The physical and chemical states of zeolite-supported TiO2 were evaluated via powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) and nitrogen adsorption-desorption isotherms. The effects of operational parameters, including TiO2 content, calcination temperature, pH, initial dye concentration, as well as catalyst dosage, on photocatalytic degradation performance were examined. The photocatalytic reaction followed first-order kinetics for all catalysts; optimum photodegradation efficiency was found to result from the use of a high TiO2 concentration (20% TiO2), a calcination temperature of 600 degrees C, alkaline pH (9-10) and a catalyst dosage of 5333 ppm. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：817 / 824
页数：8
相关论文
共 33 条
  • [1] Photocatalytic degradation of orange II by TiO2 catalysts supported on adsorbents
    Bhattacharyya, A
    Kawi, S
    Ray, MB
    [J]. CATALYSIS TODAY, 2004, 98 (03) : 431 - 439
  • [2] Treatment of aqueous effluents of the leather industry by membrane processes - A review
    Cassano, A
    Molinari, R
    Romano, M
    Drioli, E
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2001, 181 (01) : 111 - 126
  • [3] Photodegradation of dye pollutants on silica gel supported TiO2 particles under visible light irradiation
    Chen, YX
    Wang, K
    Lou, LP
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (1-2) : 281 - 287
  • [4] Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters
    Daneshvar, N
    Salari, D
    Khataee, AR
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 157 (01) : 111 - 116
  • [5] Coordination, structure, and vibrational spectra of titanium in silicates and zeolites in comparison with related molecules. An ab initio study
    deMan, AJM
    Sauer, J
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (12) : 5025 - 5034
  • [6] Factorial experimental design of Orange II photocatalytic discolouration
    Fernández, J
    Kiwi, J
    Lizama, C
    Freer, J
    Baeza, J
    Mansilla, HD
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 151 (1-3) : 213 - 219
  • [7] HETEROGENEOUS PHOTOCATALYSIS
    FOX, MA
    DULAY, MT
    [J]. CHEMICAL REVIEWS, 1993, 93 (01) : 341 - 357
  • [8] Photooxidation of the phenylazonaphthol AO20 on TIO2:: kinetic and mechanistic investigations
    Galindo, C
    Jacques, P
    Kalt, A
    [J]. CHEMOSPHERE, 2001, 45 (6-7) : 997 - 1005
  • [9] Photochemical treatment of solutions of azo dyes containing TiO2
    Gonçalves, MST
    Oliveira-Campos, AMF
    Pinto, EMMS
    Plasencia, PMS
    Queiroz, MJRP
    [J]. CHEMOSPHERE, 1999, 39 (05) : 781 - 786
  • [10] Photocatalytic decomposition of azo-dye acid black 1 in water over modified titanium dioxide
    Grzechulska, J
    Morawski, AW
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 36 (01) : 45 - 51
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