New equations for binary gas transport in porous media, Part 2: experimental validation

A previous study [Water Resour Res 39 (3) (2003) doi:10.1029/2002WR001338] questioned the validity of the traditional advection-dispersion equation for describing gas flow in porous media. In an original mathematical derivation presented in Part 1 [Adv Water Resour, this issue] we have demonstrated the theoretical existence of two novel physical phenomena which govern the macroscopic transport of gases in porous media. In this work we utilize laboratory experiments and numerical modeling in order to ascertain the importance of these novel theoretical terms. Numerical modeling results indicate that the newly derived sorptive velocity, arising from closure level coupling effects, does not contribute noticeably to the overall flux, under the conditions explored in this work. We demonstrate that the newly discovered "slip coupling" phenomenon in the mass conservation equation plays an important role in describing the physics of gas flow through porous solids for flow regimes of both environmental and industrial interest. (C) 2003 Elsevier Science Ltd. All rights reserved.