Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications

被引：229

作者：

Xue, Yuhua ^{[1
,2
,3
]}

Liu, Yong ^{[1
,2
]}

Lu, Fan ^{[1
,2
]}

Qu, Jia ^{[1
,2
]}

Chen, Hao ^{[1
,2
]}

Dai, Liming ^{[1
,2
,3
]}

机构：

[1] Wenzhou Med Coll, Sch Ophthalmol & Optometry, Inst Adv Mat Nanobio Applicat IAMNBA, Wenzhou 325027, Zhejiang, Peoples R China

[2] Wenzhou Med Coll, Hosp Eye, Wenzhou 325027, Zhejiang, Peoples R China

[3] Case Western Reserve Univ, Dept Macromol Sci & Engn, Ctr Adv Sci & Engn Carbon Case4Carbon, Cleveland, OH 44106 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2012年 / 3卷 / 12期

基金：

美国国家科学基金会;

关键词：

SURFACES; POLYMER;

D O I：

10.1021/jz3005877

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Through the amide formation between amine-functionalized polyhedral oligomeric silsesquioxane (POSS) and oxygen-containing groups (e.g., epoxy and carboxyl groups) in graphene oxide (GO), we have synthesized POSS-functionalized graphene nanosheets (POSS-graphene), which are highly soluble in various organic solvents attractive for multifunctional applications. Thin films from solution casting of the resultant POSS-graphene were found to show superhydrophobic properties with a water/air contact angle of similar to 15 degrees, while the superhydrophobic POSS-graphene powder could be used to construct liquid marbles. In addition, the POSS-graphene hybrids were also used as novel nanofillers to increase the glass transition temperature (T-g) and decompose temperature (T-d) for polymers.

引用

页码：1607 / 1612

页数：6

共 24 条

[1] Improvement of photon extraction efficiency of GaN-based LED using micro and nano complex polymer structures
Cho, Joong-Yeon
Byeon, Kyeong-Jae
Park, Hyoungwon
Kim, Jinseung
Kim, Hyeong-Seok
Lee, Heon
[J]. NANOSCALE RESEARCH LETTERS, 2011, 6 : 1 - 6
[2] The chemistry of graphene oxide
Dreyer, Daniel R.
Park, Sungjin
Bielawski, Christopher W.
Ruoff, Rodney S.
[J]. CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 228 - 240
[3] Design and creation of superwetting/antiwetting surfaces
Feng, Xinjian
Jiang, Lei
[J]. ADVANCED MATERIALS, 2006, 18 (23) : 3063 - 3078
[4] Intercalation and stitching of graphite oxide with diaminoalkanes
Herrera-Alonso, Margarita
Abdala, Ahmed A.
McAllister, Michael J.
Aksay, Ilhan A.
Prud'homme, Robert K.
[J]. LANGMUIR, 2007, 23 (21) : 10644 - 10649
[5] Ho P. K. H., 2008, ADV MATER, V20, P3440
[6] PREPARATION OF GRAPHITIC OXIDE
HUMMERS, WS
OFFEMAN, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) : 1339 - 1339
[7] Superparamagnetic Fe3O4 nanocrystals@graphene composites for energy storage devices
Li, Baojun
Cao, Huaqiang
Shao, Jin
Qu, Meizhen
Warner, Jamie H.
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) : 5069 - 5075
[8] Biocompatible Graphene Oxide-Based Glucose Biosensors
Liu, Yong
Yu, Dingshan
Zeng, Chao
Miao, Zongcheng
Dai, Liming
[J]. LANGMUIR, 2010, 26 (09) : 6158 - 6160
[9] Hierarchical Self-Assembly of Polyhedral Oligomeric Silsesquioxane End-Capped Stimuli-Responsive Polymer: From Single Micelle to Complex Micelle
Ma, Li
Geng, Haiping
Song, Jiangxuan
Li, Jinze
Chen, Guangxin
Li, Qifang
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (36) : 10586 - 10591
[10] Reduced graphene oxide by chemical graphitization
Moon, In Kyu
Lee, Junghyun
Ruoff, Rodney S.
Lee, Hyoyoung
[J]. NATURE COMMUNICATIONS, 2010, 1

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