Soft-donor dipicolinamide derivatives for selective actinide(iii)/lanthanide(iii) separation: the role of S- vs. O-donor sites

被引：40

作者：

Lehman-Andino, Ingrid ^{[1
,2
]}

Su, Jing ^{[3
]}

Papathanasiou, Konstantinos E. ^{[1
,2
]}

Eaton, Teresa M. ^{[4
,6
]}

Jian, Jiwen ^{[4
]}

Dan, David ^{[5
]}

Albrecht-Schmitt, Thomas E. ^{[5
]}

Dares, Christopher J. ^{[1
,2
]}

Batista, Enrique R. ^{[3
]}

Yang, Ping ^{[3
]}

Gibson, John K. ^{[4
]}

Kavallieratos, Konstantinos ^{[1
,2
]}

机构：

[1] Florida Int Univ, Dept Chem & Biochem, Miami, FL 33199 USA

[2] Florida Int Univ, Biomol Sci Inst, Miami, FL 33199 USA

[3] Los Alamos Natl Lab, Theoret Div, Los Alamos, NM 87545 USA

[4] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA

[5] Florida State Univ, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[6] Embry Riddle Aeronaut Univ, Prescott, AZ USA

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 17期

关键词：

ANION-PI INTERACTIONS; TRIVALENT ACTINIDES; AMERICIUM(III); EXTRACTION; LIGANDS; COMPLEXATION; LANTHANIDE; ACID; EUROPIUM(III); THIOAMIDE;

D O I：

10.1039/c8cc07683a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selectivity for An(III) vs. Ln(III) binding and extraction using dipicolinamide analogs containing the C=O vs. C=S groups was investigated in solution and the gas-phase, and by DFT calculations. The results show higher selectivity for complex formation and extraction for Am(III) vs. Eu(III) for the softer dithioamide vs. the diamide ligand, while in CH3CN the diamide binds more strongly than the thioamide to several Ln(III), forming 1:1 complexes.

引用

收藏

页码：2441 / 2444

页数：4

相关论文

共 46 条

[1] Structural versatility of anion-π interactions in halide salts with pentafluorophenyl substituted cations [J].

Albrecht, Markus ;

Wesselt, Claudia ;

de Groot, Marita ;

Rissanen, Kari ;

Luechow, Arne .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (14) :4600-+

[2] NEW DIAMIDES OF 2,2′-DIPYRIDYL-6,6′-DICARBOXYLIC ACID FOR ACTINIDE-LANTHANIDE SEPARATION [J].

Alyapyshev, M. Yu. ;

Babain, V. A. ;

Tkachenko, L. I. ;

Paulenova, A. ;

Popova, A. A. ;

Borisova, N. E. .

SOLVENT EXTRACTION AND ION EXCHANGE, 2014, 32 (02) :138-152

[3] Interaction of M3+ lanthanide cations with amide, urea, thioamide and thiourea ligands:: a quantum mechanical study [J].

Berny, F ;

Wipff, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2001, (01) :73-82

[4] Separation of americium(III) and europium(III) from nitrate medium using a binary mixture of cyanex-301 with n-donor ligands [J].

Bhattacharyya, A ;

Mohapatra, PK ;

Manchanda, VK .

SOLVENT EXTRACTION AND ION EXCHANGE, 2006, 24 (01) :1-17

[5] 1,10-Phenanthroline and Non-Symmetrical 1,3,5-Triazine Dipicolinamide-Based Ligands For Group Actinide Extraction [J].

Bisson, Julia ;

Dehaudt, Jeremy ;

Charbonnel, Marie-Christine ;

Guillaneux, Denis ;

Miguirditchian, Manuel ;

Marie, Cecile ;

Boubals, Nathalie ;

Dutech, Guy ;

Pipelier, Muriel ;

Blot, Virginie ;

Dubreuil, Didier .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (25) :7819-7829

[6] Alternatives to HDEHP and DTPA for Simplified TALSPEAK Separations [J].

Braley, Jenifer C. ;

Grimes, Travis S. ;

Nash, Kenneth L. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (02) :629-638

[7] A series of dithiocarbamates for americium, curium, and californium [J].

Cary, Samantha K. ;

Su, Jing ;

Galley, Shane S. ;

Albrecht-Schmitt, Thomas E. ;

Batista, Enrique R. ;

Ferrier, Maryline G. ;

Kozimor, Stosh A. ;

Mocko, Veronika ;

Scott, Brian L. ;

Van Alstine, Cayla E. ;

White, Frankie D. ;

Yang, Ping .

DALTON TRANSACTIONS, 2018, 47 (41) :14452-14461

[8] Covalency in Americium(III) Hexachloride [J].

Cross, Justin N. ;

Su, Jing ;

Batista, Enrique R. ;

Cary, Samantha K. ;

Evans, William J. ;

Kozimor, Stosh A. ;

Mocko, Veronika ;

Scott, Brian L. ;

Stein, Benjamin W. ;

Windorff, Cory J. ;

Yang, Ping .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (25) :8667-8677

[9] Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium [J].

Cross, Justin N. ;

Macor, Joseph A. ;

Bertke, Jeffery A. ;

Ferrier, Maryline G. ;

Girolami, Gregory S. ;

Kozimor, Stosh A. ;

Maassen, Joel R. ;

Scott, Brian L. ;

Shuh, David K. ;

Stein, Benjamin W. ;

Stieber, S. Chantal E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (41) :12755-12759

[10] Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III) [J].

Cross, Justin N. ;

Villa, Eric M. ;

Wang, Shuao ;

Juan Diwu ;

Polinski, Matthew J. ;

Albrecht-Schmitt, Thomas E. .

INORGANIC CHEMISTRY, 2012, 51 (15) :8419-8424

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