The role of Mn in the electronic structure of Ba3Ti2MnO9

被引：11
作者：
Radtke, G
Maunders, C
Lazar, S
de Groot, FMF
Etheridge, J
Botton, GA
机构：
[1] McMaster Univ, Brockhouse Inst Mat Res, Hamilton, ON L8S 4M1, Canada
[2] Monash Univ, Sch Phys & Mat Engn, Clayton, Vic 3168, Australia
[3] Delft Univ Technol, Kavli Inst Nanosci, Natl Ctr HREM, Delft, Netherlands
[4] Univ Utrecht, Dept Inorgan Chem & Catalysis, Utrecht, Netherlands
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 11期
关键词：
energy loss near edge fine structure; transition metal oxide; hexagonal perovskite; electronic structure;
D O I：
10.1016/j.jssc.2005.08.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The energy loss near edge structure (ELNES) of the O-K, Ti-L-23 and Mn-L-23 edges have been recorded in hexagonal Ba(3)Ti(2)NlnO(9) with an energy resolution of 0.10-0.20eV using a monochromator on a commercial transmission electron microscope (TEM) and compared with a tetragonal BaTiO3 reference sample. The formal valency and symmetry of Mn have been determined using atomic multiplets calculations and its effect on the electronic structure of BaTiO3 has been interpreted through a molecular-orbital model. (c) 2005 Elsevier Inc. All rights reserved.
引用
收藏
页码：3426 / 3430
页数：5
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