Experimental and theoretical study of the vibrational spectra of tin(IV) complexes based on 2-hydroxy-3,6-di-tert-butyl-para-benzoquianone

被引：15

作者：

Khamaletdinova, N. M. ^{[1
]}

Meshcheryakova, I. N. ^{[1
]}

Piskunov, A. V. ^{[1
]}

Kuznetsova, O. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 02期

关键词：

Raman spectroscopy; infrared spectroscopy; density functional theory; tin; 2-hydroxy-3,6-di-tert-butyl-para-benzoquianone; 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquianone; DERIVATIVES; HALIDES;

D O I：

10.1134/S0022476615020055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Raman spectra of tin 2-hydroxy-3,6-di-tert-butyl-para-benzoquianone complexes L2SnX2 and LSnX3 (L is 2-oxy-3,6-di-tert-butyl-para-benzoquianone; X = CH3, C2H5, n-C4H9, and C6H5) are studied. A comparative analysis of the experimental and calculated spectra is carried out and the vibrational frequencies are conventionally assigned. A new tin(IV) complex based on 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquianone (L'H-2) containing phenyl substituents at the metal atom is synthesized. Absorption bands of the complexes are interpreted in the low-frequency range of the infrared spectrum that was not considered previously.

引用

页码：233 / 242

页数：10

共 18 条

[1] Reversible binding of dioxygen by a non-transition-metal complex
Abakumov, GA
Poddel'sky, AI
Grunova, EV
Cherkasov, VK
Fukin, GK
Kurskii, YA
Abakumova, LG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (18) : 2767 - 2771
[2] Complexes of tin(IV) halides and diorganotin(IV) dihalides with 3,5-dimethyl-1-(2′-pyridyl)pyrazole
Alvarez-Boo, P
Casas, JS
Castiñeiras, A
Couce, MD
Freijanes, E
Furlani, A
Russo, U
Scarcia, V
Sordo, J
Varela, M
[J]. INORGANICA CHIMICA ACTA, 2003, 353 : 8 - 14
[3] FAR IR AND RAMAN ASSIGNMENTS OF SUBSTITUTED ARYLTRIMETHYLTINS
BISHOP, ME
SCHAEFFER, CD
ZUCKERMAN, JJ
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1976, 32 (08) : 1519 - 1537
[4] Bocker J., 1997, SPECTROSKOPIE
[5] Chumaevskii N.A., 1971, Vibrational Spectra of Heteroorganic Compounds of Group IV-B and V-B Elements
[6] DERNOVA VS, 1979, VIBRATIONAL SPECTRA
[7] Kabarova N. Yu., 1992, IZV AKAD NAUK K, V12, P2798
[8] Hypervalent tin-organic compounds: Vibrational spectroscopy in the solid as a tool for structure determination
Kolb, U
Drager, M
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1997, 53 (04) : 517 - 529
[9] Synthesis and characterisation of tin(IV) and organotin(IV) derivatives 2-{[(2-hydroxyphenyl) imino]methyl}phenol
Pettinari, C
Marchetti, F
Pettinari, R
Martini, D
Drozdov, A
Troyanov, S
[J]. INORGANICA CHIMICA ACTA, 2001, 325 (1-2) : 103 - 114
[10] Tin(IV) Complexes Based on 2-Hydroxy-3,6-Di-tert-Butyl-para-Benzoquinone: Syntheses, Structures, and Electrochemical Behavior in Solution
Piskunov, A. V.
Meshcheryakova, I. N.
Fukin, G. K.
Smolyaninov, I. V.
Khamaletdinova, N. M.
Kuznetsova, O. V.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (04) : 205 - 215

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