Tailored Ruthenium-N-Heterocyclic Carbene Hybrid Catalytic Materials for the Hydrogenation of Carbon Dioxide in the Presence of Amine

被引：28

作者：

Baffert, Mathieu ^{[1
]}

Maishal, Tarun K. ^{[1
]}

Mathey, Laurent ^{[1
]}

Coperet, Christophe ^{[1
]}

Thieuleux, Chloe ^{[1
]}

机构：

[1] Univ Lyon 1, C2P2, UMR 5265, CNRS,CPE, F-69616 Villeurbanne, France

来源：

CHEMSUSCHEM | 2011年 / 4卷 / 12期

关键词：

carbenes; heterogeneous catalysis; hydrogenation; mesoporous materials; ruthenium; FORMIC-ACID; COMPLEXES; SILICA; N; N-DIMETHYLFORMAMIDE; IMMOBILIZATION;

D O I：

10.1002/cssc.201100223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hidden depths: Heterogeneous catalysts containing single-site ruthenium-bis-N-heterocyclic carbene (NHC) species are obtained by designing tailored hybrid organic-inorganic materials and in situ transformations, leading to final Ru-NHC units. These catalysts represent promising alternatives to homogeneous complexes with comparable activities (turnover number of ca. 3000). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1762 / 1765

页数：4

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