The emergence of sulfoxides as efficient ligands in transition metal catalysis

被引：229

作者：

Sipos, Gellert ^{[1
]}

Drinkel, Emma E. ^{[1
]}

Dorta, Reto ^{[1
]}

机构：

[1] Univ Western Australia, Sch Chem & Biochem, Crawley 6009, Australia

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 11期

基金：

澳大利亚研究理事会;

关键词：

ASYMMETRIC CONJUGATE ADDITION; ARYL BORONIC ACIDS; PHOSPHINO-TERT-BUTYLSULFINAMIDE; AEROBIC OXIDATIVE CYCLIZATION; BETA-AMINO SULFOXIDES; RHODIUM I COMPLEXES; P-ALKENE LIGANDS; C-H ALKYLATION; ARYLBORONIC ACIDS; CHIRAL LIGANDS;

D O I：

10.1039/c4cs00524d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sulfoxides are capable of forming stable complexes with transition metals and there have been many comprehensive studies into their binding properties. However, the use of sulfoxides, particularly chiral sulfoxides, as ligands in transition metal catalysis is rather less well developed. This review aims to describe these catalytic studies and covers new developments that are showing very promising results and that have led to a renewed interest in this field.

引用

页码：3834 / 3860

页数：27

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