Applications of Silicon-Carbon Coupling Constants

被引：9
作者：
Blechta, Vratislav [1 ]
机构：
[1] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague 6, Suchdol, Czech Republic
来源：
ANNUAL REPORTS ON NMR SPECTROSCOPY, VOL 67 | 2009年 / 67卷
关键词：
silicon-carbon coupling constants; silicon-carbon coupling constant sign; Si-29; NMR; C-13; s-character of bond; electronegativity of substituent; s-electron densities; MULTINUCLEAR MAGNETIC-RESONANCE; SI-29; NMR-SPECTROSCOPY; SPIN-SPIN COUPLINGS; CHEMICAL-SHIFTS (1)DELTA-C-12/13(SI-29); SOLVENT-CONTROLLED REACTIONS; ULTRAHIGH-RESOLUTION NMR; LONG-RANGE COUPLINGS; X-RAY-STRUCTURE; SI-N BRIDGE; H-B BRIDGES;
D O I：
10.1016/S0066-4103(09)06702-7
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
Experimental methods used for detectior of silicon-carbon coupling constants are summarized with an emphasis on multiple-bond couplings. Values of silicon-carbon coupling constants are related to electronic structure parameters such as electronegativity of substituents, s-character of silicon-carbon bond, s-electron densities and others. Extensive tables of silicon-carbon coupling constants are given in appendices.
引用
收藏
页码：97 / 264
页数：168
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