One-Dimensional Barium Coordination Polymer With 2,2′-Bipyridine-5,5′-Dicarboxylate Ligand: Synthesis, Spectroscopic Characterization, Thermal Analyses, and Crystal Structure

被引:19
作者
Pour, Nasim Tadayon [1 ]
Khalighi, Aida [1 ]
Yousefi, Mohammad [1 ]
Amani, Vahid [1 ]
机构
[1] Islamic Azad Univ, Dept Chem, Yadegar E Imam Khomeini RAH Branch, Tehran, Iran
关键词
Ba(II); 2; 2'-bipyridine-5; 5'-dicarboxylic acid; crystal structure; thermal gravimetric; differential thermal analyses; luminescent properties; METAL-ORGANIC FRAMEWORKS; THIN-FILMS; COMPLEXES; ACID; 1,10-PHENANTHROLINE; DIVERSITY; IRON(III); CHLORIDE; HISTORY; IONS;
D O I
10.1080/15533174.2013.862822
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
[Ba(5,5 '-dcbipy)(-H2O)(2)(H2O)(2)](n) (1) complex was obtained from the reaction of one equivalent of 2,2'-bipyridine-5,5'-dicarboxylic acid (5,5 '-dcbipy.H-2) and one equivalent of ethylene diamine (en) with one equivalent of BaCl2.2H(2)O in water. This complex was characterized by elemental analysis, IR, UV-Vis, and luminescence spectroscopy and its structure was studied by the single-crystal X-ray diffraction method. The thermal stability of 1 was studied by thermogravimetric and differential thermal analyses.
引用
收藏
页码:1427 / 1433
页数:7
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