A New 3D Pillar-Layered Zn(II) Coordination Polymer Constructed From the Mixed Flexible Polycarboxylate and Bis (pyridyl)-Based Ligands

被引：1

作者：

Liu, Huimin ^{[1
]}

机构：

[1] Agr Univ Hebei, Coll Sci, Baoding 071001, Hebei, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 11期

关键词：

Zn(II) compound; hydrothermal synthesis; pillar-layered framework; luminescence; METAL-ORGANIC FRAMEWORKS; STRUCTURAL VARIATIONS; DESIGN; ACID;

D O I：

10.1080/15533174.2015.1137048

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new Zn(II) coordination polymer, namely [Zn-3(TTHA)(bpp)(H2O)(3)](n)center dot 4n(H2O) (1 H(6)TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid, bpp = 1,3-di(4-pyridyl)propane), has been synthesized by the hydrothermal self-assembly of Zn(NO3)(2)center dot 6H(2)O, H6TTHA and bpp. Single-crystal x-ray diffraction analysis reveals that compound 1 features a 3D framework, which can be described as the 2D layers constructed by the Zn(II) ions and TTHA(6)-ligands pillared by the bpp ligands. Furthermore, the thermal stability and luminescent property of compound 1 were investigated.

引用

页码：1652 / 1655

页数：4

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