Salen-Cu(II)@MIL-101(Cr) as an efficient heterogeneous catalyst for cycloaddition of CO2 to epoxides under mild conditions

被引：22

作者：

Liu, Caijuan ^{[1
,2
]}

Liu, Xiao-Huan ^{[1
,2
]}

Li, Bo ^{[1
,2
]}

Zhang, Lei ^{[3
]}

Ma, Jian-Gong ^{[1
,2
]}

Cheng, Peng ^{[1
,2
]}

机构：

[1] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China

[2] Nankai Univ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China

[3] Nankai Univ, Sch Elect Informat & Opt Engn, Tianjin 300350, Peoples R China

来源：

JOURNAL OF ENERGY CHEMISTRY | 2017年 / 26卷 / 05期

关键词：

Metal-organic frameworks; Carbon dioxide cycloaddition; Cyclic carbonate; Heterogeneous catalyst; CARBON-DIOXIDE; CYCLIC CARBONATES; COMPLEXES; FIXATION; BOTTLE; SHIP;

D O I：

10.1016/j.jechem.2017.07.022

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A double active center system, namely Salen-Cu(II)@MIL-101(Cr), was successfully synthesized via the "ship in a bottle" approach, which acted as a bifunctional material for both capture and conversion of CO2 in a single process. For the first time, Salen-Cu(II)@MIL-101(Cr) catalyst was developed for the synthesis of propylene carbonate from CO2 and propylene oxide under room temperature and ambient pressure with a yield of 87.8% over 60 h. Furthermore, the reaction mechanism was also discussed. (C) 2017 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

引用

页码：821 / 824

页数：4

共 21 条

[1] Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2
Aresta, Michele
Dibenedetto, Angela
Angelini, Antonella
[J]. CHEMICAL REVIEWS, 2014, 114 (03) : 1709 - 1742
[2] Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a 'bottle around the ship' approach
Bogaerts, Thomas
Van Yperen-De Deyne, Andy
Liu, Ying-Ya
Lynen, Frederic
Van Speybroeck, Veronique
Van Der Voort, Pascal
[J]. CHEMICAL COMMUNICATIONS, 2013, 49 (73) : 8021 - 8023
[3] Metal-Organic Frameworks as Efficient Heterogeneous Catalysts for the Regioselective Ring Opening of Epoxides
Dhakshinamoorthy, Amarajothi
Alvaro, Mercedes
Garcia, Hermenegildo
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (28) : 8530 - 8536
[4] Organic solvent-free process for the synthesis of propylene carbonate from supercritical carbon dioxide and propylene oxide catalyzed by insoluble ion exchange resins
Du, Y
Cai, F
Kong, DL
He, LN
[J]. GREEN CHEMISTRY, 2005, 7 (07) : 518 - 523
[5] A chromium terephthalate-based solid with unusually large pore volumes and surface area
Férey, G
Mellot-Draznieks, C
Serre, C
Millange, F
Dutour, J
Surblé, S
Margiolaki, I
[J]. SCIENCE, 2005, 309 (5743) : 2040 - 2042
[6] Cycloaddition of epoxides and CO2 catalyzed by bisimidazole-functionalized porphyrin cobalt(III) complexes
Jiang, Xu
Gou, Faliang
Chen, Fengjuan
Jing, Huanwang
[J]. GREEN CHEMISTRY, 2016, 18 (12) : 3567 - 3576
[7] Mixed-Linker Metal-Organic Frameworks as Catalysts for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2
Kleist, Wolfgang
Jutz, Fabian
Maciejewski, Marek
Baiker, Alfons
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (24) : 3552 - 3561
[8] Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes
Kondratenko, Evgenii V.
Mul, Guido
Baltrusaitis, Jonas
Larrazabal, Gaston O.
Perez-Ramirez, Javier
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (11) : 3112 - 3135
[9] Cooperative calcium-based catalysis with 1,8-diazabicyclo[5.4.0]-undec-7-ene for the cycloaddition of epoxides with CO2 at atmospheric pressure
Liu, Xi
Zhang, Shuai
Song, Qing-Wen
Liu, Xiao-Fang
Ma, Ran
He, Liang-Nian
[J]. GREEN CHEMISTRY, 2016, 18 (09) : 2871 - 2876
[10] Catalytic activity of metal organic framework Cu3(BTC)2 in the cycloaddition of CO2 to epichlorohydrin reaction
Macias, Eugenia E.
Ratnasamy, Paul
Carreon, Moises A.
[J]. CATALYSIS TODAY, 2012, 198 (01) : 215 - 218

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