Photochemical stability of π-conjugated polymers for polymer solar cells: a rule of thumb

被引：225
作者：
Manceau, Matthieu [1 ]
Bundgaard, Eva [1 ]
Carle, Jon E. [1 ]
Hagemann, Ole [1 ]
Helgesen, Martin [1 ]
Sondergaard, Roar [1 ]
Jorgensen, Mikkel [1 ]
Krebs, Frederik C. [1 ]
机构：
[1] Tech Univ Denmark, Riso Natl Lab Sustainable Energy, DK-4000 Roskilde, Denmark
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 12期
关键词：
BAND-GAP POLYMERS; PHOTOVOLTAIC PERFORMANCE; SEMICONDUCTING POLYMERS; POLY(2,7-CARBAZOLE); DECOMPOSITION; ALDEHYDES; ABSENCE; FILMS; P3HT;
D O I：
10.1039/c0jm03105d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A comparative photochemical stability study of a wide range of pi-conjugated polymers relevant to polymer solar cells is presented. The behavior of each material has been investigated under simulated sunlight (1 sun, 1000 W m(-2), AM 1.5G) and ambient atmosphere. Degradation was monitored during ageing combining UV-visible and infrared spectroscopies. From the comparison of the collected data, the influence of the polymer chemical structure on its stability has been discussed. General rules relative to the polymer structure-stability relationship are proposed.
引用
收藏
页码：4132 / 4141
页数：10
相关论文
共 43 条
  • [1] [Anonymous], AM1 5 STAND DAT
  • [2] PHOTOCHEMICAL BEHAVIOR OF SEMIAROMATIC POLYAMIDES
    ARNAUD, R
    FANTON, E
    GARDETTE, JL
    [J]. POLYMER DEGRADATION AND STABILITY, 1994, 45 (03) : 361 - 369
  • [3] Primary photochemical reactions. Part VII. Photochemical decomposition of isovaleraldehyde and di-n-propyl ketone.
    Bamford, CH
    Norrish, RGW
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1935, : 1504 - 1511
  • [4] Spectral Engineering in π-Conjugated Polymers with Intramolecular Donor-Acceptor Interactions
    Beaujuge, Pierre M.
    Amb, Chad M.
    Reynolds, John R.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (11) : 1396 - 1407
  • [5] Solar-Energy Production and Energy-Efficient Lighting: Photovoltaic Devices and White-Light-Emitting Diodes Using Poly(2,7-fluorene), Poly(2,7-carbazole), and Poly(2,7-dibenzosilole) Derivatives
    Beaupre, Serge
    Boudreault, Pierre-Luc T.
    Leclerc, Mario
    [J]. ADVANCED MATERIALS, 2010, 22 (08) : E6 - +
  • [6] Copolymers of Cyclopentadithiophene and Electron-Deficient Aromatic Units Designed for Photovoltaic Applications
    Bijleveld, Johan C.
    Shahid, Munazza
    Gilot, Jan
    Wienk, Martijn M.
    Janssen, Rene A. J.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (20) : 3262 - 3270
  • [7] Toward a rational design of poly(2,7-carbazole) derivatives for solar cells
    Blouin, Nicolas
    Michaud, Alexandre
    Gendron, David
    Wakim, Salem
    Blair, Emily
    Neagu-Plesu, Rodica
    Belletete, Michel
    Durocher, Gilles
    Tao, Ye
    Leclerc, Mario
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) : 732 - 742
  • [8] Low band gap polymers for organic photovoltaics
    Bundgaard, Eva
    Krebs, Frederik C.
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (11) : 954 - 985
  • [9] Low Band Gap Polymers for Roll-to-Roll Coated Polymer Solar Cells
    Bundgaard, Eva
    Hagemann, Ole
    Manceau, Matthieu
    Jorgensen, Mikkel
    Krebs, Frederik C.
    [J]. MACROMOLECULES, 2010, 43 (19) : 8115 - 8120
  • [10] Low band gap polymers based on 1,4-dialkoxybenzene, thiophene, bithiophene donors and the benzothiadiazole acceptor
    Carle, Jon Eggert
    Andreasen, Jens Wenzel
    Jorgensen, Mikkel
    Krebs, Frederik Christian
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (05) : 774 - 780
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