A Mechanically Robust and Highly Ion-Conductive Polymer-Blend Coating for High-Power and Long-Life Lithium-Ion Battery Anodes

被引：174
|
作者：
Li, Fu-Sheng [1 ]
Wu, Yu-Shiang [2 ]
Chou, Jackey [3 ]
Winter, Martin [4 ]
Wu, Nae-Lih [1 ]
机构：
[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 106, Taiwan
[2] China Univ Sci & Technol, Dept Mech Engn, Taipei 115, Taiwan
[3] Long Time Technol Corp, New Taipei City 221, Taiwan
[4] Univ Munster, Inst Phys Chem, MEET Battery Res Ctr, D-48149 Munster, Germany
来源：
ADVANCED MATERIALS | 2015年 / 27卷 / 01期
关键词：
SOLID-ELECTROLYTE INTERPHASE; GRAPHITE NEGATIVE ELECTRODE; CARBONACEOUS MATERIALS; ARTIFICIAL GRAPHITE; RATE CAPABILITY; SURFACE-AREA; CHARGE LOSS; CYCLE LIFE; CELLS; SEI;
D O I：
10.1002/adma.201403880
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A mechanically robust and ion-conductive polymeric coating containing two polymers, polyethylene glycol tert-octylphenyl ether and poly(allyl amine), with four tailored functional groups is developed for graphite and graphite-Si composite anodes. The coating, acting as an artificial solid electrolyte interphase, leads to remarkable enhancement in capacity reversibility and cycling stability, as well as a high-rate performance of the studied anodes. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：130 / 137
页数：8
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