Nanostructured catalysts in fuel cells

被引:181
作者
Qiao, Yan
Li, Chang Ming [1 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
关键词
DIRECT ELECTRON-TRANSFER; GLUCOSE/O-2 BIOFUEL CELL; WALLED CARBON NANOTUBES; HIGH ELECTROCATALYTIC ACTIVITY; OXYGEN REDUCTION ACTIVITY; DIRECT ELECTROCHEMISTRY; PT-RU; METHANOL ELECTROOXIDATION; MESOPOROUS CARBONS; TITANIA NANOTUBES;
D O I
10.1039/c0jm02871a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fuel cells are promising green power sources with theoretically zero pollution and broad applications. One of the most important challenges for fuel cells is to have more cost-effective catalysts with high catalytic activity. Nanoscience has stimulated extensive interest in nanostructured catalysts to significantly improve the energy density, power density and operation reliability while greatly reducing the manufacturing expense. In particular, nanostructured materials play a critical role in the catalysis of various innovative fuel cells, which not only possess high specific surface area and good conductivity for low polarization, but also provide unique nanoporous structures and functional chemical properties for highly intrinsic electroactivity and excellent utilization. The recent advances in nanostructured catalysts and supports are reviewed in this article. The relationships between the nanostructures and electrocatalytic performance and the catalysis mechanisms are discussed.
引用
收藏
页码:4027 / 4036
页数:10
相关论文
共 110 条
[21]   Direct electrochemistry of hemoglobin on carbonized titania nanotubes and its application in a sensitive reagentless hydrogen peroxide biosensor [J].
Guo, Chunxian ;
Hu, Fengping ;
Li, Chang Ming ;
Shen, Pei Kang .
BIOSENSORS & BIOELECTRONICS, 2008, 24 (04) :819-824
[22]   Novel Te/Pt Hybrid Nanowire with Nanoporous Surface: A Catalytically Active Nanoelectrocatalyst [J].
Guo, Shaojun ;
Dong, Shaojun ;
Wang, Erkang .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (11) :4797-4802
[23]   Three-Dimensional Pt-on-Pd Bimetallic Nanodendrites Supported on Graphene Nanosheet: Facile Synthesis and Used as an Advanced Nanoelectrocatalyst for Methanol Oxidation [J].
Guo, Shaojun ;
Dong, Shaojun ;
Wang, Erkang .
ACS NANO, 2010, 4 (01) :547-555
[24]   Tin/platinum bimetallic nanotube array and its electrocatalytic activity for methanol oxidation [J].
Guo, YG ;
Hu, JS ;
Zhang, HM ;
Liang, HP ;
Wan, LJ ;
Bai, CL .
ADVANCED MATERIALS, 2005, 17 (06) :746-+
[25]   Functionalization of electrochemically prepared titania nanotubes with Pt for application as catalyst for fuel cells [J].
Hassan, Fathy M. B. ;
Nanjo, Hiroshi ;
Venkatachalam, Shanmugam ;
Kanakubo, Mitsuhiro ;
Ebina, Takeo .
JOURNAL OF POWER SOURCES, 2010, 195 (18) :5889-5895
[26]   Electrochemical properties of Pt-modified nano-honeycomb diamond electrodes [J].
Honda, K ;
Yoshimura, M ;
Rao, TN ;
Tryk, DA ;
Fujishima, A ;
Yasui, K ;
Sakamoto, Y ;
Nishio, K ;
Masuda, H .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 514 (1-2) :35-50
[27]   Highly Stable Pd-Based Catalytic Nanoarchitectures for Low Temperature Fuel Cells [J].
Hu, F. P. ;
Shen, P. K. ;
Li, Y. L. ;
Liang, J. Y. ;
Wu, J. ;
Bao, Q. L. ;
Li, C. M. ;
Wei, Z. D. .
FUEL CELLS, 2008, 8 (06) :429-435
[28]   Entrapment of enzymes and carbon nanotubes in biologically synthesized silica:: Glucose oxidase-catalyzed direct electron transfer [J].
Ivnitski, Dmitri ;
Artyushkova, Kateryna ;
Rincon, Rosalba A. ;
Atanassov, Plamen ;
Luckarift, Heather R. ;
Johnson, Glenn R. .
SMALL, 2008, 4 (03) :357-364
[29]   Glucose oxidase anode for biofuel cell based on direct electron transfer [J].
Ivnitski, Dmitri ;
Branch, Brittany ;
Atanassov, Plamen ;
Apblett, Christopher .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (08) :1204-1210
[30]   Nanostructured Pt Dispersed on Graphene-Multiwalled Carbon Nanotube Hybrid Nanomaterials as Electrocatalyst for PEMFC [J].
Jafri, R. Imran ;
Arockiados, T. ;
Rajalakshmi, N. ;
Ramaprabhu, S. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (06) :B874-B879