UV-enhanced atomic layer deposition of ZrO2 thin films at room temperature

被引:27
作者
Lee, Byoung H. [1 ]
Cho, Sangho [1 ]
Hwang, Jae K. [1 ]
Kim, Su H. [1 ]
Sung, Myung M. [1 ]
机构
[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea
关键词
Atomic layer deposition; ZrO2; Self-limiting reaction; UV-ALD; PET; THERMAL BARRIER COATINGS; GROWTH-KINETICS; TITANIUM-OXIDE; GAS-TRANSPORT; SILICON; SIO2; PHOTOIRRADIATION; PRECURSORS; EPITAXY; TIO2;
D O I
10.1016/j.tsf.2010.03.059
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A UV-enhanced atomic layer deposition (UV-ALD) process was developed to deposit ZrO2 thin films on poly (ethylene terephthalate) (PET) polymer substrates using zirconium tetra-tert-butoxide (ZTB) and H2O as precursors with UV light. In the UV-ALD process, the surface reactions were found to be self-limiting and complementary enough to yield uniform, conformal, and pure ZrO2 thin films on polymer substrates at room temperature. The UV light was very effective to obtain the high-quality ZrO2 thin films with good adhesive strength on polymer substrates. The ZrO2 thin films exhibit large-scale uniformity, sharp interfaces, and unique electrical properties. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:6432 / 6436
页数:5
相关论文
共 26 条
[1]   Growth kinetics and structure formation of ZrO2 thin films in chloride-based atomic layer deposition process [J].
Aarik, J ;
Aidla, A ;
Mändar, H ;
Uustare, T ;
Sammelselg, V .
THIN SOLID FILMS, 2002, 408 (1-2) :97-103
[2]   Atomic layer deposition of SiO2 and TiO2 in alumina tubular membranes:: Pore reduction and effect of surface species on gas transport [J].
Cameron, MA ;
Gartland, IP ;
Smith, JA ;
Diaz, SF ;
George, SM .
LANGMUIR, 2000, 16 (19) :7435-7444
[3]   Synthesis of ZrO2 thin films by atomic layer deposition:: growth kinetics, structural and electrical properties [J].
Cassir, M ;
Goubin, F ;
Bernay, C ;
Vernoux, P ;
Lincot, D .
APPLIED SURFACE SCIENCE, 2002, 193 (1-4) :120-128
[4]   Highly conformal ZrO2 deposition for dynamic random access memory application [J].
Chang, JP ;
Lin, YS .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (06) :2964-2969
[5]   Structure and stability of ultrathin zirconium oxide layers on Si(001) [J].
Copel, M ;
Gribelyuk, M ;
Gusev, E .
APPLIED PHYSICS LETTERS, 2000, 76 (04) :436-438
[6]   SiOx gas barrier coatings on polymer substrates:: Morphology and gas transport considerations [J].
Erlat, AG ;
Spontak, RJ ;
Clarke, RP ;
Robinson, TC ;
Haaland, PD ;
Tropsha, Y ;
Harvey, NG ;
Vogler, EA .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (29) :6047-6055
[7]   Low-temperature Al2O3 atomic layer deposition [J].
Groner, MD ;
Fabreguette, FH ;
Elam, JW ;
George, SM .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :639-645
[8]   LOW-TEMPERATURE SURFACE CLEANING OF SILICON AND ITS APPLICATION TO SILICON MBE [J].
ISHIZAKA, A ;
SHIRAKI, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (04) :666-671
[9]   THERMAL BARRIER COATINGS FOR JET ENGINE IMPROVEMENT [J].
JOHNER, G ;
SCHWEITZER, KK .
THIN SOLID FILMS, 1984, 119 (03) :301-315
[10]  
JUKLI K, 2000, CHEM VAPOR DEPOS, V6, P297