Calcium Oxalates: Thermodynamic and Kinetic Conditions of Their Formation in the Presence of Organic Components

被引：2

作者：

Korolkov, Vyacheslav V. ^{[1
]}

Golovanova, Olga A. ^{[1
]}

Kuimova, Marina ^{[2
]}

机构：

[1] Omsk FM Dostoevsky State Univ, Omsk, Russia

[2] Natl Res Tomsk Polytech Univ, Tomsk, Russia

来源：

BIOGENIC-ABIOGENIC INTERACTIONS IN NATURAL AND ANTHROPOGENIC SYSTEMS | 2016年

关键词：

Crystallization; Calcium oxalate; Thermodynamic simulation; Kinetics; Amino acids; STABILITY-CONSTANTS; METAL-COMPLEXES; URINARY STONES; AMINO-ACIDS; SIDE-CHAINS;

D O I：

10.1007/978-3-319-24987-2_37

中图分类号：

Q14 [生态学（生物生态学）];

学科分类号：

071012 ; 0713 ;

摘要：

The paper researches a range of problems related to the peculiarities of calcium oxalate crystallization in the presence of amino acids on the bases of thermodynamic calculations and experimental data. The regularities of phase formation in the system Ca2+-C2O42--H2O-amino acid in a widely variable interval of component concentrations and pH are theoretically researched. The influence of pH on the thermodynamic stability of crystalline compounds is considered. The kinetic parameters of crystallization are determined: the induction period, the rate constant, the order of crystals' growth, and the influence of amino acids on the kinetics of crystallization of calcium oxalate is established.

引用

页码：485 / 500

页数：16

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