Facile synthesis of novel SrO 0.5:MnO 0.5 bimetallic oxide nanostructure as a high-performance electrode material for supercapacitors

被引:18
作者
Adimule, Vinayak [1 ]
Bhat, Vinay S. [2 ]
Yallur, Basappa C. [3 ]
Gowda, Adarsha H. J. [4 ]
De Padova, Paola [5 ,6 ]
Hegde, Gurumurthy [7 ,10 ]
Toghan, Arafat [8 ,9 ]
机构
[1] Angadi Inst Technol & Management AITM, Belagavi, India
[2] BMS Coll Engn, Ctr Nanomat & Displays, Bangalore, Karnataka, India
[3] Ramaiah Inst Technol, Bangalore, Karnataka, India
[4] Natl Univ Ireland, Ctr Res Med Devices, Galway, Ireland
[5] Ist Struttura Mat CNR ISM CNR, Rome, Italy
[6] INFN LNF, Rome, Italy
[7] Christ Deemed Univ, Dept Chem, Bengaluru, India
[8] South Valley Univ, Fac Sci, Dept Chem, Qena, Egypt
[9] Imam Mohammad Ibn Saud Islamic Univ IMSIU, Coll Sci, Dept Chem, Riyadh, Saudi Arabia
[10] Christ Deemed Univ, Ctr Adv Res & Dev CARD, Bengaluru, India
关键词
Nanostructures; SrO (0.5); MnO (0.5); co-precipitation; supercapacitor; energy storage; electrochemical; bimetallic; ELECTROCHEMICAL PROPERTIES; NANOPARTICLES; TIO2; INTERCALATION; COMPOSITES; PHOTOANODE; EFFICIENT; GRAPHENE; SURFACE; MN3O4;
D O I
10.1177/18479804211064028
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Perovskite bimetallic oxides as electrode material blends can be an appropriate method to enhance the supercapacitor properties. In the present research, SrO (0.5):MnO (0.5) nanostructures (NS) were synthesized by a facile co-precipitation method and calcinated at 750-800 degrees C. Crystal structure of SrO (0.5):MnO (0.5) NS were characterized by X-ray diffraction, surface chemical composition and chemical bond analysis, and dispersion of SrO into MnO was confirmed by X-ray photoelectron spectral studies. Structural morphology was analyzed from scanning electron microscopy. Optical properties of SrO (0.5):MnO (0.5) NS were studied using UV-Visible spectrophotometer and SrO (0.5) and MnO (0.5) NS showed similar to 75 nm grain, similar to 64 nm grain boundary distance, with two maxima at 261 nm and 345 nm as intensity of absorption patterns, respectively. The synthesized SrO (0.5):MnO (0.5) NS exhibited high specific capacitance of 392.8 F/g at a current density of 0.1 A/g. Electrochemical impedance spectroscopy results indicated low resistance and very low time constant of 0.2 s similar to 73% of the capacitance was retained after 1000 galvanostatic charge-discharge (GCD) cycles. These findings indicate that SrO (0.5):MnO (0.5) bimetallic oxide material could be a promising electrode material for electrochemical energy storage systems.
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页数:14
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