Study of the catalytic pyrolysis behaviour of polyethylene-polypropylene mixtures

被引:65
作者
Marcilla, A [1 ]
García-Quesada, JC [1 ]
Sánchez, S [1 ]
Ruiz Femenia, R [1 ]
机构
[1] Univ Alicante, Dept Chem Engn, Alicante 03690, Spain
关键词
catalytic pyrolysis; polyethylene-polypropylene mixtures; thermogravimetric study;
D O I
10.1016/j.jaap.2004.10.005
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the present work, a thermogravimetric study of the influence of different catalysts on the decomposition of HDPE and PP mixtures has been carried out and compared with the thermal decomposition behaviour. In the absence of catalyst, the mixtures exhibit an overlapping of the processes of decomposition of both polymers. The catalysts employed (HZSM5, a fluid catalytic cracking zeolite and HUSY) modify in a different way the catalytic cracking of HDPE and PP. The FCC catalyst is the system yielding the maximum separation of the decomposition processes under the conditions studied. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:387 / 392
页数:6
相关论文
共 20 条
[11]   HZSM5 and HUSY deactivation during the catalytic pyrolysis of polyethylene [J].
Marcilla, A ;
Beltrán, MI ;
Hernández, F ;
Navarro, R .
APPLIED CATALYSIS A-GENERAL, 2004, 278 (01) :37-43
[12]   Catalytic pyrolysis of polypropylene using MCM-41:: kinetic model [J].
Marcilla, A ;
Gómez, A ;
Reyes-Labarta, JA ;
Giner, A .
POLYMER DEGRADATION AND STABILITY, 2003, 80 (02) :233-240
[13]  
Moore E. P, 1996, POLYPROPYLENE HDB PO
[14]   Thermal and catalytic decomposition of polyethylene and polypropylene [J].
Onu, P ;
Vasile, C ;
Ciocîlteu, S ;
Iojoiu, E ;
Darie, H .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 49 (1-2) :145-153
[15]   Catalytic degradation of polyethylene over solid acid catalysts [J].
Park, DW ;
Hwang, EY ;
Kim, JR ;
Choi, JK ;
Kim, YA ;
Woo, HC .
POLYMER DEGRADATION AND STABILITY, 1999, 65 (02) :193-198
[16]   Catalytic conversion of polystyrene over HMCM-41, HZSM-5 and amorphous SiO2-Al2O3:: comparison with thermal cracking [J].
Serrano, DP ;
Aguado, J ;
Escola, JM .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2000, 25 (2-3) :181-189
[17]   Investigation of the catalytic pyrolysis of high-density polyethylene over a HZSM-5 catalyst in a laboratory fluidized-bed reactor [J].
Sharratt, PN ;
Lin, YH ;
Garforth, AA ;
Dwyer, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (12) :5118-5124
[18]   SIMULTANEOUS THERMOGRAVIMETRIC MASS-SPECTROMETRIC STUDIES OF THE THERMAL-DECOMPOSITION OF BIO-POLYMERS .1. AVICEL CELLULOSE IN THE PRESENCE AND ABSENCE OF CATALYSTS [J].
VARHEGYI, G ;
ANTAL, MJ ;
SZEKELY, T ;
TILL, F ;
JAKAB, E .
ENERGY & FUELS, 1988, 2 (03) :267-272
[19]  
WENWEI Z, 1996, POLYM DEGRAD STABIL, V1, P129
[20]   Study of selected thermal characteristics of polypropylene/polyethylene binary blends using DSC and TGA [J].
Wong, ACY ;
Lam, F .
POLYMER TESTING, 2002, 21 (06) :691-696