A novel one-dimensional framework material constructed from antimony-substituted polyoxovanadium clusters:: [(C2N2H10)2β-{Sb8IIIV14IVO42(H2O)}](C2N2H8)•4H2O

被引：46

作者：

Hu, XX

Xu, JQ

Cui, XB

Song, JF

Wang, TG

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Perparat Chem, Changchun 130023, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 02期

基金：

中国国家自然科学基金;

关键词：

polyoxometalate; antimony; crystal structure; hydrothermal synthesis;

D O I：

10.1016/j.inoche.2003.11.019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel polyoxovanadate containing antimony [(C2N2H10)2beta-{Sb(III)8V(14)(IV)O(42)(H2O)}](C2N2H8)(.)4H(2)O has been synthesized from a mixture Of VOSO4, Sb2O3, en and H2O under hydrothermal conditions. The spherical [beta-{Sb(III)8(14)(IV) O-42(H2O)}](4-) clusters form a one-dimensional double-chain structure with non-bonding Sb...O contacts, (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：264 / 267

页数：4

共 15 条

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