Synthesis, photo- and electroluminescent properties of norbornene based platinum-containing copolymers

被引：19
作者：
Begantsova, Yulya E. [1 ]
Bochkarev, Leonid N. [1 ]
Malysheva, Irina P. [1 ]
Stolyarova, Natalia E. [1 ]
Kurskii, Yurii A. [1 ]
Lopatin, Mikhail A. [1 ]
Baranov, Evgenii V. [1 ]
Ilichev, Vasilii A. [1 ]
Abakumov, Gleb A. [1 ]
Bochkarev, Mikhail N. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
来源：
SYNTHETIC METALS | 2011年 / 161卷 / 11-12期
基金：
俄罗斯基础研究基金会;
关键词：
Platinum; Copolymer; ROMP; Electroluminescence; Photoluminescence; LIGHT-EMITTING-DIODES; METATHESIS POLYMERIZATION; CONJUGATED POLYMERS; COMPLEXES; EFFICIENT; PHOTOLUMINESCENCE; FLUORESCENCE; PHOTOPHYSICS; CATALYSTS; LIGANDS;
D O I：
10.1016/j.synthmet.2011.03.013
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Norbornene based monomers containing the 2-phenylpyridinato-N,C(2') platinum(II) complex bonded by acetylacetonate or pyrazolonate anchor groups were synthesized and copolymerized with a carbazole-containing norbornene comonomer by ring-opening metathesis polymerization (ROMP). The photo- and electroluminescence spectra of the resulting Pt-copolymers are similar. They consist of broad bands with maxima at 495, 530 and 565 nm which arise from the mixed ligand centered (LC) and metal to ligand charge transfer (MLCT) transitions. The copolymer with the cyclometalated platinum(II) complex bonded to the polymer chain via the pyrazolonate anchor group revealed the highest brightness of electroluminescence (260 cd/m(2) at 21 V). (c) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1043 / 1050
页数：8
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