Hydrogenation of methyl benzoate over Mn/Al catalysts: Comparison among catalyst preparation routes

被引：6
作者：
Chen, AM
Xu, HL
Hua, WM
Shen, W
Yue, YH [1 ]
Gao, Z
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
来源：
TOPICS IN CATALYSIS | 2005年 / 35卷 / 1-2期
关键词：
methyl benzoate; hydrogenation; benzaldehyde; manganese oxide catalyst; hydrotalcite-like compound; mesoporous molecular sieve;
D O I：
10.1007/s11244-005-3822-4
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Mn/Al catalysts for hydrogenation of methyl benzoate to benzaldehyde were prepared by different methods. The catalyst prepared from hydrotalcite-like precursor, the mesoporous MSU-gamma supported Mn catalyst and the Mn-incorporated MSU-gamma catalyst are more active than conventional Mn/gamma-Al(2)O(3) catalyst. The reaction temperature for the same yield level can be reduced by 20-60 degrees C. High specific surface area, high dispersion of manganese oxide species and strong interaction of manganese oxide species with gamma-Al(2)O(3) are of benefit to the reaction.
引用
收藏
页码：177 / 185
页数：9
相关论文
共 25 条
  • [1] SYNTHESIS OF HEXAGONALLY PACKED MESOPOROUS TIO2 BY A MODIFIED SOL-GEL METHOD
    ANTONELLI, DM
    YING, JY
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (18): : 2014 - 2017
  • [2] Synthesis and characterization of hexagonally packed mesoporous tantalum oxide molecular sieves
    Antonelli, DM
    Ying, JY
    [J]. CHEMISTRY OF MATERIALS, 1996, 8 (04) : 874 - 881
  • [3] Mesoporous alumina molecular sieves
    Bagshaw, SA
    Pinnavaia, TJ
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (10): : 1102 - 1105
  • [4] Cabrera S, 1999, ADV MATER, V11, P379, DOI 10.1002/(SICI)1521-4095(199903)11:5<379::AID-ADMA379>3.0.CO
  • [5] 2-6
  • [6] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS
    Cavani, F.
    Trifiro, F.
    Vaccari, A.
    [J]. CATALYSIS TODAY, 1991, 11 (02) : 173 - 301
  • [7] Support effect in hydrogenation of methyl benzoate over supported manganese oxide catalysts
    Chen, AM
    Xu, HL
    Yue, YH
    Hua, WM
    Shen, W
    Gao, Z
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) : 299 - 306
  • [8] Deoxygenation of benzoic acid on metal oxides - 1. The selective pathway to benzaldehyde
    de Lange, MW
    van Ommen, JG
    Lefferts, L
    [J]. APPLIED CATALYSIS A-GENERAL, 2001, 220 (1-2) : 41 - 49
  • [9] Glbein A.P., 1986, US Pat, Patent No. 4585899
  • [10] Holderich W.F., 1993, STUD SURF SCI CATAL, V75, P27
123