Enantioselective Organocatalytic Intramolecular Morita-Baylis-Hillman Reaction of Some Unusual Substrates

被引：19
|
作者：
Satpathi, Bishnupada [1 ]
Ramasastry, S. S. V. [1 ]
机构：
[1] IISER Mohali, Organ Synth & Catalysis Lab, Dept Chem Sci, Sect 81,Manuali PO, Sas Nagar 140306, Punjab, India
来源：
SYNLETT | 2016年 / 27卷 / 15期
关键词：
Morita-Baylis-Hillman reaction; heterocyclic compounds; organocatalysis; cyclopentannulation; natural products; ASYMMETRIC-SYNTHESIS; CATALYZED REACTIONS; SECONDARY-AMINES; DOMINO REACTION; PHOSPHINE; CONSTRUCTION; CYCLIZATION; CHEMISTRY; ALDEHYDES; SOLVENTS;
D O I：
10.1055/s-0035-1562489
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The hypothesis and rationale behind our recent contribution towards the development of an enantioselective organocatalytic intramolecular Morita-Baylis-Hillman (IMBH) reaction, leading to the synthesis of an array of cyclopentannulated arenes and heteroarenes, is discussed. The latest advancement has addressed some of the shortcomings of the MBH reaction. In addition, it is believed that this study paves the way for the consideration of new possibilities in MBH chemistry.
引用
收藏
页码：2178 / 2182
页数：5
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