Cyclic adsorption of water vapour on CuBTC MOF: Sustaining the hydrothermal stability under non-equilibrium conditions

被引:40
作者
Al-Janabi, Nadeen [1 ]
Martis, Vladimir [2 ]
Servi, Nektaria [2 ]
Siperstein, Flor R. [1 ]
Fan, Xiaolei [1 ]
机构
[1] Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester M13 9PL, Lancs, England
[2] Surface Measurement Syst Ltd, Unit 5,Rosemont Rd, London HA0 4PE, England
关键词
Metal-organic frameworks (MOFs); CuBTC; Water vapour adsorption; Non-equilibrium adsorption; Hydrothermal stability; Cyclic adsorption; METAL-ORGANIC FRAMEWORKS; CU-BTC; CO2; ADSORPTION; CARBON-DIOXIDE; SEPARATION; HKUST-1; NANOTUBES; ADSORBENT; HYDROGEN; STORAGE;
D O I
10.1016/j.cej.2017.09.197
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Metal organic frameworks (MOFs) based adsorption processes for gas separation from humid streams are limited by the hydrothermal stability of MOFs. This work presents a comprehensive study of the hydrothermal stability of CuBTC (BTC=benzene-1,3,5-tricarboxylate) MOF when exposed to humid streams in cyclic operations. We show that water uptake is slow, and that adsorption processes will most likely operate under non-equilibrium conditions. CuBTC does not show signs of decomposition when exposed to low water concentration and room temperature (up to water partial pressures of 6 mbar and 25 degrees C) for up to 48 h of cyclic operation. Nevertheless, short cycles (of less than 15 min per pressure stage) are required when exposed to high water vapour content (up to 70 mbar, 50 degrees C). This work demonstrates the need of tailoring the length of water exposure to avoid the equilibrium adsorption of water vapour on CuBTC and maintain the adsorbent integrity.
引用
收藏
页码:594 / 602
页数:9
相关论文
共 49 条
[1]   A Facile Post-Synthetic Modification Method To Improve Hydrothermal Stability and CO2 Selectivity of CuBTC Metal-Organic Framework [J].
Al-Janabi, Nadeen ;
Deng, Haoran ;
Borges, Jayane ;
Liu, Xufei ;
Garforth, Arthur ;
Siperstein, Flor R. ;
Fan, Xiaolei .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (29) :7941-7949
[2]   Underlying mechanism of the hydrothermal instability of Cu3(BTC)2 metal-organic framework [J].
Al-Janabi, Nadeen ;
Alfutimie, Abdullatif ;
Siperstein, Flor R. ;
Fan, Xiaolei .
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING, 2016, 10 (01) :103-107
[3]   Mapping the Cu-BTC metal-organic framework (HKUST-1) stability envelope in the presence of water vapour for CO2 adsorption from flue gases [J].
Al-Janabi, Nadeen ;
Hill, Patrick ;
Torrente-Murciano, Laura ;
Garforth, Arthur ;
Gorgojo, Patricia ;
Siperstein, Flor ;
Fan, Xiaolei .
CHEMICAL ENGINEERING JOURNAL, 2015, 281 :669-677
[4]   Water Stability and Adsorption in Metal-Organic Frameworks [J].
Burtch, Nicholas C. ;
Jasuja, Himanshu ;
Walton, Krista S. .
CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612
[5]   Impact of Alkyl-Functionalized BTC on Properties of Copper-Based Metal-Organic Frameworks [J].
Cai, Yang ;
Zhang, Yadong ;
Huang, Yougui ;
Marder, Seth R. ;
Walton, Krista S. .
CRYSTAL GROWTH & DESIGN, 2012, 12 (07) :3709-3713
[6]   Insights into the Adsorption of Water and Small Alcohols on the Open-Metal Sites of Cu-BTC via Molecular Simulation [J].
Calero, S. ;
Gomez-Alvarez, P. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (01) :467-472
[7]   Understanding Water Adsorption in Cu-BTC Metal-Organic Frameworks [J].
Castillo, Juan Manuel ;
Vlugt, Thijs J. H. ;
Calero, Sofia .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (41) :15934-15939
[8]   Metal organic framework adsorbent for biogas upgrading [J].
Cavenati, Simone ;
Grande, Carlos A. ;
Rodrigues, Alirio E. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (16) :6333-6335
[9]   A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations [J].
Chen, Qiang ;
Chang, Ze ;
Song, Wei-Chao ;
Song, Han ;
Song, Hai-Bin ;
Hu, Tong-Liang ;
Bu, Xian-He .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (44) :11550-11553
[10]  
Chui S. S., 1999, SCIENCE, V283