B-site doping of lanthanum strontium titanate for solid oxide fuel cell anodes

被引:74
作者
Miller, David N. [1 ]
Irvine, John T. S. [1 ]
机构
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
基金
英国工程与自然科学研究理事会;
关键词
Perovskite; Strontium titanate; SOFC; Anode; EXTENDED DEFECTS; CONDUCTIVITY;
D O I
10.1016/j.jpowsour.2010.11.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study the properties of the compounds La0.33Sr0.67Ti0.92X0.08O3+delta where X = Al3+, Ga3+, Fen+, Mg2+, Mnn+ and Sc3+, have been investigated in the search for alternative solid oxide fuel cell anodes. The choice of dopant controls the structure, redox properties, conductivity and electrocatalytic properties of the compound. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:7323 / 7327
页数:5
相关论文
共 13 条
[1]   Sc-substituted oxygen excess titanates as fuel electrodes for SOFCs [J].
Canales-Vázquez, J ;
Ruiz-Morales, JC ;
Irvine, JTS ;
Zhou, WZ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (07) :A1458-A1465
[2]   Studies on the reorganization of extended defects with increasing n in the perovskite-based La4Srn-4TinO3n+2 series [J].
Canales-Vázquez, J ;
Smith, MJ ;
Irvine, JTS ;
Zhou, WZ .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (06) :1000-1008
[3]   Electrical properties in La2Sr4Ti6O19-δ:: a potential anode for high temperature fuel cells [J].
Canales-Vázquez, J ;
Tao, SW ;
Irvine, JTS .
SOLID STATE IONICS, 2003, 159 (1-2) :159-165
[4]  
Canales-Vazquez J., 2003, THESIS U ST ANDREWS
[5]   Development of anode material based on La-substituted SrTiO3 perovskites doped with manganese and/or gallium for SOFC [J].
Escudero, M. J. ;
Irvine, J. T. S. ;
Daza, L. .
JOURNAL OF POWER SOURCES, 2009, 192 (01) :43-50
[6]   The stability and mixed conductivity in La and Fe doped SrTiO3 in the search for potential SOFC anode materials [J].
Fagg, DP ;
Kharton, VV ;
Kovalevsky, AV ;
Viskup, AP ;
Naumovich, EN ;
Frade, JR .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1831-1835
[7]   Effect of fabrication parameters on the electrical conductivity of YxSr1-xTiO3 for anode materials [J].
Huang, Xianliang ;
Zhao, Hailei ;
Shen, Wei ;
Qiu, Weihua ;
Wu, Weijiang .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2006, 67 (12) :2609-2613
[8]  
Marina O.A., 2002, 5 EUR SOL OX FUEL CE
[9]   Thermal, electrical, and electrocatalytical properties of lanthanum-doped strontium titanate [J].
Marina, OA ;
Canfield, NL ;
Stevenson, JW .
SOLID STATE IONICS, 2002, 149 (1-2) :21-28
[10]   Mn-substituted titanates as efficient anodes for direct methane SOFCs [J].
Ovalle, Alejandro ;
Ruiz-Morales, Juan Carlos ;
Canales-Vazquez, Jesus ;
Marrero-Lopez, David ;
Irvine, John T. S. .
SOLID STATE IONICS, 2006, 177 (19-25) :1997-2003