Ionic conduction in glass: New information on the interrelation between the "Jonscher behavior" and the "nearly constant-loss behavior" from broadband conductivity spectra

被引:95
作者
Roling, B
Martiny, C
Murugavel, S
机构
[1] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany
[2] Univ Munster, Sonderforsch Bereich 458, D-48149 Munster, Germany
关键词
D O I
10.1103/PhysRevLett.87.085901
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We analyze broadband ac conductivity spectra of various ion conducting glasses with regard to the composition dependence of the "Jonscher behavior" and of the "nearly constant-loss behavior." In the temperature range of our experiments (173 K less than or equal to T less than or equal to 573 K), both types of behavior are closely related, indicating that both arise from ion hopping. However, the "nearly constant-loss behavior" observed at temperatures below 100 K seems to be caused by other dynamic processes.
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页码:85901 / 1
页数:4
相关论文
共 38 条
[11]   Is there a mixed alkali effect in the low temperature ac conductivity of glasses? [J].
Jain, H ;
Lu, X .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 196 :285-290
[12]  
Jain H, 1997, J AM CERAM SOC, V80, P517, DOI 10.1111/j.1151-2916.1997.tb02862.x
[13]  
Jonscher A. K., 1983, DIELECTRIC RELAXATIO
[14]   UNIVERSAL DIELECTRIC RESPONSE [J].
JONSCHER, AK .
NATURE, 1977, 267 (5613) :673-679
[15]   STUDY OF LOW-FREQUENCY EXCITATIONS IN DISORDERED SOLIDS BY NUCLEAR-MAGNETIC-RESONANCE AND ELECTRICAL-CONDUCTIVITY [J].
KANERT, O ;
KUCHLER, R ;
DIECKHOFER, J ;
LU, X ;
JAIN, H ;
NGAI, KL .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 172 (pt 2) :1277-1284
[16]   HOPPING CONDUCTION AND SUPERIONIC CONDUCTORS [J].
KIMBALL, JC ;
ADAMS, LW .
PHYSICAL REVIEW B, 1978, 18 (10) :5851-5858
[17]  
KOHLER F, 1972, LIQUID STATE, P163
[19]   LIMITING BEHAVIOR OF AC CONDUCTIVITY IN IONICALLY CONDUCTING CRYSTALS AND GLASSES - A NEW UNIVERSALITY [J].
LEE, WK ;
LIU, JF ;
NOWICK, AS .
PHYSICAL REVIEW LETTERS, 1991, 67 (12) :1559-1561
[20]   Origin of constant loss in ionic conductors [J].
León, C ;
Rivera, A ;
Várez, A ;
Sanz, J ;
Santamaria, J ;
Ngai, KL .
PHYSICAL REVIEW LETTERS, 2001, 86 (07) :1279-1282