Introduction to Spatial Anion Control for Direct C-H Arylation

被引：4

作者：

Dhankhar, Jyoti ^{[1
]}

Coric, Ilija ^{[1
]}

机构：

[1] Univ Zurich, Dept Chem, Winterthurerstr 190, CH-8057 Zurich, Switzerland

来源：

SYNLETT | 2022年 / 33卷 / 06期

关键词：

C-H activation; concerted metalation-deprotonation; CMD; C-H arylation; spatial anion control; palladium; CATALYZED DIRECT ARYLATION; SIMPLE ARENES; AROMATIC-SUBSTITUTION; ELECTROPHILIC SUBSTITUTION; COUPLING REACTIONS; BOND ACTIVATION; PALLADIUM; FUNCTIONALIZATION; MECHANISM; SILVER;

D O I：

10.1055/s-0040-1719860

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is demonstrated that the crossover between gas- and liquid-like regions on the phase diagram of the Lennard-Jones system occurs at a fixed value of the density divided by its value at the freezing point, ρ/ρfr ≃ 0.35. This definition is consistent with other definitions proposed recently. As a result, a very simple practical expression for the gas-to-liquid crossover line emerges. © 2022 Author(s).

引用

页码：503 / 512

页数：10

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