Aluminum Metal-Organic Framework Triggers Carbon Dioxide Reduction Activity

被引：21
|
作者：
Lee, Michelle [1 ,2 ,3 ]
De Riccardis, Alberto [1 ,2 ,4 ]
Kazantsev, Roman, V [1 ,2 ]
Cooper, Jason K. [1 ,2 ]
Buckley, Aya K. [1 ,2 ,5 ]
Burroughs, Paul W. W. [1 ,2 ,5 ]
Larson, David M. [1 ,2 ]
Mele, Giuseppe [4 ]
Toma, Francesca M. [1 ,2 ]
机构：
[1] Lawrence Berkeley Natl Lab, Joint Ctr Artificial Photosynth, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA
[3] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
[4] Univ Salento, Dept Engn Innovat, I-73100 Lecce, Italy
[5] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
ACS APPLIED ENERGY MATERIALS | 2020年 / 3卷 / 02期
关键词：
metal-organic framework; CO2; reduction; electrocatalysis; aluminum; confined environment; selectivity; ELECTROCHEMICAL REDUCTION; CO2; REDUCTION; FORMIC-ACID; CATALYSIS;
D O I：
10.1021/acsaem.9b02210
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Confinement of metal centers is a powerful tool to manipulate reactivity and tune selectivity in chemical transformations. While aluminum as a foil is inactive for carbon dioxide reduction and shows high selectivity for the hydrogen evolution reaction, here we show that aluminum confined in a metal-organic framework (MOF), MIL-53(Al), suppresses hydrogen evolution reaction activity and enhances carbon dioxide reduction. This aluminum MOF can produce up to 40% faradaic efficiency for carbon monoxide and formic acid. This study demonstrates that the unique reaction environment created by the MOF enables changes in reaction selectivity and can impart atypical catalytic capabilities to metals.
引用
收藏
页码：1286 / 1291
页数：11
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