Insight into chirality on molecular stacking for tunable ultralong organic phosphorescence

被引：18
作者：
Ma, Chaoqun [1 ,2 ]
Ma, Huili [1 ,2 ]
Ling, Kun [1 ,2 ]
Zheng, Ruilin [3 ]
Gu, Mingxing [1 ,2 ]
Song, Lulu [1 ,2 ]
An, Zhongfu [1 ,2 ]
Shi, Huifang [1 ,2 ]
Huang, Wei [1 ,2 ,4 ]
机构：
[1] Nanjing Tech Univ, NanjingTech, Key Lab Flexible Elect KLOFE, 30 South Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, NanjingTech, IAM, 30 South Puzhu Rd, Nanjing 211800, Jiangsu, Peoples R China
[3] Nanjing Univ Posts & Telecommun, Coll Elect & Opt Engn, Wenyuan Rd, Nanjing 210023, Jiangsu, Peoples R China
[4] NPU, SIFE, 127 West Youyi Rd, Xian 710072, Shaanxi, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY C | 2018年 / 6卷 / 38期
基金：
中国国家自然科学基金;
关键词：
ROOM-TEMPERATURE PHOSPHORESCENCE; PERSISTENT LUMINESCENCE; OXYGEN; EMISSION; FLUORESCENCE; POLYLACTIDE; LIGHT; NANOPARTICLES; LIFETIME; FILMS;
D O I：
10.1039/c8tc03297a
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new levorotatory compound ((S)-9,9'-(6-(1-phenylethoxy)-1,3,5-triazine-2,4-diyl)bis(9H-carbazole)) and its corresponding racemic compound show different intermolecular interactions to restrain nonradiative transition, resulting in an enhanced ultralong organic phosphorescence lifetime from 229.0 ms to 419.8 ms. This work will provide a new insight into the chirality of organic molecules to adjust the ultralong phosphorescence.
引用
收藏
页码：10179 / 10183
页数：5
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