Quantifying Bulk and Surface Recombination in CdTe Solar Cells Using Time-Resolved Terahertz Spectroscopy

被引:0
|
作者
Taheri, Mohammad M. [1 ]
Truong, Triet M. [1 ]
Fields, Shannon [2 ]
Shafarman, William N. [2 ]
McCandless, Brian E. [2 ]
Baxter, Jason B. [1 ]
机构
[1] Drexel Univ, Dept Chem & Biol Engn, Philadelphia, PA 19104 USA
[2] Univ Delaware, Inst Energy Convers, Newark, DE 19716 USA
关键词
cadmium telluride; thin film devices; photovoltaic cells; semiconductor materials; carrier dynamics;
D O I
10.1109/PVSC43889.2021.9518559
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Understanding the nature of recombination mechanisms is essential for higher power conversion efficiency in photovoltaic (PV) devices. Here we use a combination of time-resolved terahertz spectroscopy and numerical modeling to determine the bulk Shockley-Read-Hall lifetime and interface and back surface recombination velocities in CdTe thin film stacks. The measurement was facilitated by fabricating wire-grid device structures using conventional laser scribing. Evaluation of a glass/FTO/SnO2/CdS/CdTe stack treated with CdCl2 allowed separation of the CdTe absorber bulk lifetime, 1.6 ns, from the back surface recombination velocity, similar to 6x10(4) cm/s, and indicated that CdTe/CdS interface recombination velocity had no significant impact on carrier dynamics.
引用
收藏
页码:648 / 651
页数:4
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