Stabilization of ferroelectric phase in tungsten capped Hf0.8Zr0.2O2

被引:72
作者
Karbasian, Golnaz [1 ]
dos Reis, Roberto [2 ]
Yadav, Ajay K. [1 ]
Tan, Ava J. [1 ]
Hu, Chenming [1 ]
Salahuddin, Sayeef [1 ,3 ]
机构
[1] Univ Calif Berkeley, Dept Elect Engn & Comp Sci, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Mol Foundry, Berkeley, CA 94720 USA
[3] Lawrence Berkeley Natl Lab, Energy Storage & Distributed Resources Div, 1 Cyclotron Rd, Berkeley, CA 94720 USA
关键词
NEGATIVE CAPACITANCE; HFO2; FILMS; ZRO2;
D O I
10.1063/1.4993739
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report on the stabilization of the ferroelectric phase in Hf0.8Zr0.2O2 with a tungsten capping layer. Ferroelectricity is obtained in both metal-insulator-metal (MIM) and metal-insulator-semiconductor (MIS) capacitors with highly-doped Si serving as the bottom electrode in the MIS structure. Ferroelectricity is confirmed from both the electrical polarization-voltage (P-V) measurement and X-Ray Diffraction analysis that shows the presence of an orthorhombic phase. High-resolution Transmission Electron Microscopy and Energy Dispersive X-ray spectroscopy show minimal diffusion of W into the underlying Hf0.8Zr0.2O2 after the crystallization anneal. This is in contrast to significant Ti and N diffusion observed in ferroelectric HfxZr1-xO2 commonly capped with TiN. Published by AIP Publishing.
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页数:4
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