The first asymmetric synthesis of trialkyl phosphates on the basis of dynamic kinetic resolution in the phosphite method using a chiral source in a catalytic manner

被引：15

作者：

Hayakawa, Y ^{[1
]}

Hyodo, M ^{[1
]}

Kimura, K ^{[1
]}

Kataoka, M ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Human Informat, Bioorgan Chem Lab, Chikusa Ku, Nagoya, Aichi 4648601, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 14期

关键词：

D O I：

10.1039/b304163h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first asymmetric synthesis of trialkyl phosphates having stereogenic phosphorus atoms on the basis of dynamic kinetic resolution using a chiral source in a catalytic manner; achieved through the stereospecific oxidation of a trialkyl phosphite enantioselectively obtained by the condensation of a racemic unsymmetrically substituted dialkyl phosphorochloridite and an alcohol using a chiral amine as a catalytic promoter.

引用

页码：1704 / 1705

页数：2

共 45 条

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