New and efficient selenium reagents for stereoselective selenenylation reactions

被引:62
作者
Fragale, G
Neuburger, M
Wirth, T
机构
[1] Univ Basel, Inst Organ Chem, CH-4056 Basel, Switzerland
[2] Univ Basel, Inst Anorgan Chem, Lab Kristallog, CH-4056 Basel, Switzerland
关键词
D O I
10.1039/a804264k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The simple substitution of an aryl proton by a methoxy substituent improves the selectivity of the stereoselective selenenylation reaction dramatically, leading to addition products with diastereomeric ratios up to 50:1 in the methoxyselenenylation reaction of styrene.
引用
收藏
页码:1867 / 1868
页数:2
相关论文
共 13 条
  • [11] Wirth T, 1998, SYNTHESIS-STUTTGART, P162
  • [12] Mechanistic course of the asymmetric methoxyselenenylation reaction
    Wirth, T
    Fragale, G
    Spichty, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (14) : 3376 - 3381
  • [13] Wirth T, 1997, LIEBIGS ANN-RECL, P2189