Solvothermal Synthesis, Crystal Structures, and Magnetic Properties of Two Organically Templated Iron Sulfates with Chain Structures

被引：2
|
作者：
Ma, Ling [1 ]
Liu, Dan [2 ]
Xing, Yan [1 ]
Liu, Xianchun [1 ]
Li, Gaijuan [1 ]
机构：
[1] NE Normal Univ, Coll Chem, Changchun 130024, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 15期
关键词：
Iron; Sulfates; Chain structures; Solvothermal synthesis; X-ray diffraction; HYDROTHERMAL SYNTHESIS; METAL SULFATES; KAGOME; NETWORK; HYBRID;
D O I：
10.1002/zaac.201000152
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new one-dimensional (ID) organically templated iron(III) sulfates [C2NH8](3) [Fe-3(mu(3)-O)(2)(SO4)(4)] (1) and [C2N2H10][C2NH7](0.5)[FeF(SO4)(2)] (2) were synthesized under solvo-thermal conditions and characterized by single-crystal X-ray diffraction, powder X-ray diffraction (XRD), FT-IR spectroscopy, elemental analyses, ICP analyses, and thermogravimetric analyses. Single-crystal structure analysis reveals that both compounds show linear-chain structures, involving FeO6 (FeF2O4) octahedra and SO4 tetrahedra. The magnetic properties of the two compounds have also been investigated.
引用
收藏
页码：2681 / 2685
页数：5
相关论文
共 50 条
  • [21] Syntheses, Crystal Structures, and Thermal Behaviors of Two New Metallo-Organically Templated Pentaborates
    Yang, Yang
    Wang, Yu
    Zhu, Jiang
    Liu, Rui-Bin
    Xu, Jun
    Meng, Chang-Gong
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (06): : 735 - 740
  • [22] Hydrothermal Syntheses, Crystal Structures and Thermal Properties of Two New Organically Templated Open-framework Gallium Phosphites
    Zhou Guang-peng
    Yang Yu-lin
    Fan Rui-qing
    Xie Jia-qing
    Quan Xue-jun
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2013, 29 (02) : 201 - 205
  • [23] Hydrothermal syntheses, crystal structures and thermal properties of two new organically templated open-framework gallium phosphites
    Guang-peng Zhou
    Yu-lin Yang
    Rui-qing Fan
    Jia-qing Xie
    Xue-jun Quan
    Chemical Research in Chinese Universities, 2013, 29 : 201 - 205
  • [24] Amine-templated linear vanadium sulfates with different chain structures
    Paul, G
    Choudhury, A
    Nagarajan, R
    Rao, CNR
    INORGANIC CHEMISTRY, 2003, 42 (06) : 2004 - 2013
  • [25] Syntheses, characterizations and crystal structures of three new organically templated or organically bonded zinc selenates
    Feng, ML
    Mao, JG
    Song, JL
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (10) : 3529 - 3535
  • [26] Synthesis, X-ray Structures, and Luminescent Properties of Three Organically Templated Copper(I) Halides via in situ Solvothermal Reduction Reactions
    Xin, Bingjing
    Li, Yun
    Zeng, Guang
    Peng, Yu
    Li, Guanghua
    Shi, Zhan
    Feng, Shouhua
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (3-4): : 611 - 617
  • [27] Synthesis, crystal structures and magnetic properties of two iron (II) tris(pyridyl)phosphine selenides complexes
    Hu, Xuecheng
    Sun, Tingquan
    Zheng, Chunyang
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2018, 193 (05) : 300 - 305
  • [28] Two nickel(II) carboxyphosphonates with different supramolecular structures: synthesis, crystal structures and magnetic properties
    Zhu, Yan Yu
    Zhang, Xu
    Zhou, Ya Nan
    Sun, Zhen Gang
    Jiao, Cheng Qi
    TRANSITION METAL CHEMISTRY, 2021, 46 (08) : 593 - 600
  • [29] Two nickel(II) carboxyphosphonates with different supramolecular structures: synthesis, crystal structures and magnetic properties
    Yan Yu Zhu
    Xu Zhang
    Ya Nan Zhou
    Zhen Gang Sun
    Cheng Qi Jiao
    Transition Metal Chemistry, 2021, 46 : 593 - 600
  • [30] Solvothermal synthesis and crystal structures of two new copper(II) terephthalates
    Yang, BP
    Zeng, HY
    Mao, JG
    Guo, GC
    Huang, JS
    Dong, ZC
    TRANSITION METAL CHEMISTRY, 2003, 28 (05) : 600 - 605
12345