Electrochemical deposition of a carbon nanotube-poly(o-phenylenediamine) composite on a stainless steel surface

被引：36

作者：

Salam, M. Abdel ^{[1
]}

Al-Juaid, S. S. ^{[1
]}

Qusti, A. H. ^{[1
]}

Hermas, A. A. ^{[1
]}

机构：

[1] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia

来源：

SYNTHETIC METALS | 2011年 / 161卷 / 1-2期

关键词：

Carbon nanotubes; Composite; Electrodeposition; Passivation; Poly(o-phenylenediamine); CONDUCTIVE POLYMER; CORROSION INHIBITION; PASSIVE FILM; NANOTUBES; POLYANILINE; PROTECTION; PLATINUM; METALS;

D O I：

10.1016/j.synthmet.2010.11.014

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrodeposition of a nano-composite made of oxidized carbon nanotubes (CNTs) and a conductive polymer such as poly(o-phenylenediamine) (PoPD) on a stainless steel surface from aqueous solution was carried out by cyclic voltammetry. The presence of the CNTs enhanced the deposition of the PoPD and this enhancement was more significant in the presence of single walled carbon nanotubes (sCNT) by comparison to multi-walled carbon nanotubes (mCNT). Scanning electron microscope images indicated the incorporation of the CNTs in the PoPD layer. The nano-composite layer as well as the pure PoPD layer keeps the stainless steel in a passive state in acidic solution. The oxide film underneath the nano-composite layer is unique and showed high corrosion resistance in concentrated chloride solutions, which was confirmed by the presence of high contents of iron and chromium components. These findings suggest that the CNTs indirectly assist the passivation of the stainless steel by catalyic oxygen reduction and polymer oxidation process. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：153 / 157

页数：5

共 29 条

[1] Can carbon nanotubes be considered useful tools for biological applications? [J].

Bianco, A ;

Prato, M .

ADVANCED MATERIALS, 2003, 15 (20) :1765-1768

[2] Nanotube nanodevice [J].

Collins, PG ;

Zettl, A ;

Bando, H ;

Thess, A ;

Smalley, RE .

SCIENCE, 1997, 278 (5335) :100-103

[3] Electrochemical deposition of poly(o-phenylenediamine) films on type 304 stainless steel [J].

D'Elia, LF ;

Ortíz, RL ;

Márquez, OP ;

Márquez, J ;

Martínez, Y .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (04) :C297-C300

[4] MODIFICATION OF THE ELECTROCHEMICAL AND CORROSION BEHAVIOR OF STAINLESS-STEELS WITH AN ELECTROACTIVE COATING [J].

DEBERRY, DW .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (05) :1022-1026

[5] Storage of hydrogen in single-walled carbon nanotubes [J].

Dillon, AC ;

Jones, KM ;

Bekkedahl, TA ;

Kiang, CH ;

Bethune, DS ;

Heben, MJ .

NATURE, 1997, 386 (6623) :377-379

[6] Protection of steel against corrosion in aggressive medium by surface modification with multilayer polyaniline-based composite film [J].

Galkowski, M ;

Malik, MA ;

Kulesza, PJ ;

Bala, H ;

Miecznikowski, K ;

Wlodarczyk, R ;

Adamczyk, L ;

Chojak, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (06) :B249-B253

[7]

Gasparac R, 2001, J ELECTROCHEM SOC, V148, pB138, DOI 10.1149/1.1354615

[8] XPS analysis of the passive film formed on austenitic stainless steel coated with conductive polymer [J].

Hermas, A. A. .

CORROSION SCIENCE, 2008, 50 (09) :2498-2505

[9] Protection of type 430 stainless steel against pitting corrosion by ladder conductive polymer [J].

Hermas, A. A. .

PROGRESS IN ORGANIC COATINGS, 2008, 61 (01) :95-102

[10] Electrochemical coating of stainless steel with multi-walled carbon nanotubes/polyaniline composite layer [J].

Hermas, Abou-Elhagag A. ;

Salam, Mohamed Abdel ;

Al-Juaid, Salih S. ;

Al-Thabaiti, S.A. .

International Journal of Nanomanufacturing, 2009, 4 (1-4) :166-174

← 1 2 3 →