Coupled effects of flow field geometry and diffusion media material structure on evaporative water removal from polymer electrolyte fuel cells

被引:31
作者
Cho, Kyu Taek [1 ]
Mench, Matthew M. [1 ]
机构
[1] Penn State Univ, Dept Mech & Nucl Engn, Fuel Cell Dynam & Diagnost Lab, University Pk, PA 16802 USA
基金
美国国家科学基金会;
关键词
Polymer electrolyte fuel cell; Diffusion media; Gas purge; Evaporation; Flow field structure; Neutron radiography; INHOMOGENEOUS COMPRESSION; TRANSPORT PHENOMENA; PERFORMANCE; DEGRADATION; PEMFC; TEMPERATURE; DESIGN; MODEL; PEFC; DURABILITY;
D O I
10.1016/j.ijhydene.2010.07.156
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work the coupled effects of flow field geometry and diffusion media (DM) material structure on evaporative water removal during gas purge are investigated with the ex situ test methods developed in previous works [31 32] Three different flow field structures with various land to channel width ratios (L/C) were utilized with paper and cloth type DM to understand the impact of L/C and DM properties on evaporative water removal rate water distribution in DM purge efficiency and irreducible saturation In the capillary flow dominant regime it was determined that evaporative water removal is not significantly affected by L/C or DM properties and can be semi empirically correlated with critical purge time The cloth type DM was found to be superior to paper type to mitigate the in plane impedance of the land on water removal In addition to the ex situ evaporative tests neutron radiography was utilized to visualize the in situ water removal behavior Results validate a novel purge protocol suggested by the authors in a previous study to achieve a more efficient and durable gas purge that preserves membrane durability (C) 2010 Professor T Nejat Veziroglu Published by Elsevier Ltd All rights reserved
引用
收藏
页码:12329 / 12340
页数:12
相关论文
共 44 条
[1]  
BARTON RH, 2005, Patent No. 6960401
[2]   Scientific aspects of polymer electrolyte fuel cell durability and degradation [J].
Borup, Rod ;
Meyers, Jeremy ;
Pivovar, Bryan ;
Kim, Yu Seung ;
Mukundan, Rangachary ;
Garland, Nancy ;
Myers, Deborah ;
Wilson, Mahlon ;
Garzon, Fernando ;
Wood, David ;
Zelenay, Piotr ;
More, Karren ;
Stroh, Ken ;
Zawodzinski, Tom ;
Boncella, James ;
McGrath, James E. ;
Inaba, Minoru ;
Miyatake, Kenji ;
Hori, Michio ;
Ota, Kenichiro ;
Ogumi, Zempachi ;
Miyata, Seizo ;
Nishikata, Atsushi ;
Siroma, Zyun ;
Uchimoto, Yoshiharu ;
Yasuda, Kazuaki ;
Kimijima, Ken-ichi ;
Iwashita, Norio .
CHEMICAL REVIEWS, 2007, 107 (10) :3904-3951
[3]  
Bradean R., 2006, ECS T, V3, P1159
[4]   Convenient two-dimensional model for design of fuel channels for proton exchange membrane fuel cells [J].
Chen, FL ;
Wen, YZ ;
Chu, HS ;
Yan, WM ;
Soong, CY .
JOURNAL OF POWER SOURCES, 2004, 128 (02) :125-134
[5]   Effects of water removal on the performance degradation of PEMFCs repetitively brought to <0°C [J].
Cho, EA ;
Ko, JJ ;
Ha, HY ;
Hong, SA ;
Lee, KY ;
Lim, TW ;
Oh, IH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (05) :A661-A665
[6]   Effect of material properties on evaporative water removal from polymer electrolyte fuel cell diffusion media [J].
Cho, Kyu Taek ;
Mench, Matthew M. .
JOURNAL OF POWER SOURCES, 2010, 195 (19) :6748-6757
[7]   Fundamental characterization of evaporative water removal from fuel cell diffusion media [J].
Cho, Kyu Taek ;
Mench, Matthew M. .
JOURNAL OF POWER SOURCES, 2010, 195 (12) :3858-3869
[8]   Durability and degradation issues of PEM fuel cell components [J].
de Bruijn, F. A. ;
Dam, V. A. T. ;
Janssen, G. J. M. .
FUEL CELLS, 2008, 8 (01) :3-22
[9]  
Dine LLV, 2003, Procedure for shutting down a fuel cell system having an anode exhuast recycle loop, Patent No. [US6514635B2, 6514635]
[10]  
Fuss RL, 2002, U.S. Patent, Patent No. 6358637