A mixed-metal single-molecule magnet:: [Mn8Fe4O12(O2CCH2Cl)16(H2O)4]

被引:11
作者
Yang, CI
Tsai, HL [1 ]
Lee, GH
Wur, CS
Yang, SF
机构
[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan
[2] Natl Taiwan Univ, Coll Sci, Instumentat Ctr, Taipei 10601, Taiwan
[3] Natl Cheng Kung Univ, Dept Phys, Tainan 70101, Taiwan
关键词
D O I
10.1246/cl.2005.288
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis, X-ray crystal structure and magnetic properties of a new single-molecule magnet [Mn(8)Fe4O(12)-(O2CCH2Cl)(16)(H2O)4](.)2CH(2)ClCOOH(.)2CH(2)Cl(2) (3(.)2CH(2)-ClCOOH(.)2CH(2)Cl(2)) are reported. Reduced magnetization data of complex 3 indicate an S = 4 ground state, and the out-of-phase components of AC magnetic susceptibilities have frequency dependent maxima.
引用
收藏
页码:288 / 289
页数:2
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