Bis(1,2,3,4-η4-anthracene)ferrate(1-):: A paramagnetic homoleptic polyarene transition-metal anion

被引：60

作者：

Brennessel, William W. ^{[1
]}

Jilek, Robert E. ^{[1
]}

Ellis, John E. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 32期

关键词：

arene ligands; diene ligands; iron; negative-valent complexes; sandwich complexes;

D O I：

10.1002/anie.200701353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Magnetic personalities: [Fe(η4-C 14H10)2]- is an unprecedented example of an anionic 17-electron homoleptic polyarene transition-metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides "naked" atomic Fe-1 in its reaction with 1,3-butadiene to yield the first structurally authenticated homoleptic bis(1,3-butadiene) metal complex, [Fe(η4-C4H 6)2]_ (see structure). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6132 / 6136

页数：5

共 53 条

[11] Tris(η4-naphthalene)- and tris(1-4-η4-anthracene)tantalate(1_):: First homoleptic arene complexes of anionic tantalum [J].

Brennessel, WW ;

Ellis, JE ;

Pomije, MK ;

Sussman, VJ ;

Urnezius, E ;

Young, VG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (35) :10258-10259

[12]

Brennessel WW, 2002, ANGEW CHEM INT EDIT, V41, P1211, DOI 10.1002/1521-3773(20020402)41:7<1211::AID-ANIE1211>3.0.CO

[13]

2-I

[14]

BRENNESSEL WW, 2006, ANGEW CHEM, V118, P7426

[15]

BRENNESSEL WW, UNPUB

[16] REACTIVE PI-COMPLEXES OF ELECTRON-RICH TRANSITION-METALS .13. (ETA(6)-HEXALKYLBENZENE)(ETA(4)-NAPHTHALENE)IRON COMPLEXES - SYNTHESIS, PROPERTIES, STRUCTURE AND REACTIVITY [J].

BRODT, C ;

NIU, SQ ;

PRITZKOW, H ;

STEPHAN, M ;

ZENNECK, U .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 459 (1-2) :283-291

[17] THE REACTION OF[PPN][HFE(CO)(4)] WITH STYRENE IN THF - AN UNEXPECTED AND FACILE SYNTHESIS OF [PPN](2)[FE-2(CO)(8)] [J].

BRUNET, JJ ;

NEIBECKER, D ;

SRIVASTAVA, RS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 461 (1-2) :169-172

[18] VARIATIONS IN MOLECULAR GEOMETRY ALONG ISOELECTRONIC SERIES CO2(CO)8,[FECO(CO)8]-, AND [FE2(CO)8]2- [J].

CHIN, HB ;

SMITH, MB ;

WILSON, RD ;

BAU, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (16) :5285-5287

[19] SYNTHESIS AND REACTIVITY OF BIS(ETA-1,4-DI-TERT-BUTYLBUTA-1,3-DIENE)COBALT - THE X-RAY CRYSTAL-STRUCTURE OF THE ANIONIC BUTADIENE SANDWICH COMPLEX [K(18-CROWN-6)(THF)2] [CO(ETA-C4H4BUT2)2] [J].

CLOKE, FGN ;

HITCHCOCK, PB ;

MCCAMLEY, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) :248-250

[20] CONFORMATIONS OF FUSED CYCLOALKANES IN ORGANOMETALLIC COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF TRICYCLO[6.3.0.02,7]UNDECA-3,5-DIENETRICARBONYLIRON, (C11H14)FE(CO)3 [J].

COTTON, FA ;

DAY, VW ;

FRENZ, BA ;

HARDCAST.KI ;

TROUP, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (14) :4522-4528

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