Bis(1,2,3,4-η4-anthracene)ferrate(1-):: A paramagnetic homoleptic polyarene transition-metal anion

被引：60

作者：

Brennessel, William W. ^{[1
]}

Jilek, Robert E. ^{[1
]}

Ellis, John E. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 32期

关键词：

arene ligands; diene ligands; iron; negative-valent complexes; sandwich complexes;

D O I：

10.1002/anie.200701353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Magnetic personalities: [Fe(η4-C 14H10)2]- is an unprecedented example of an anionic 17-electron homoleptic polyarene transition-metal complex. This species is the first isolable homoleptic polyarene iron complex. It provides "naked" atomic Fe-1 in its reaction with 1,3-butadiene to yield the first structurally authenticated homoleptic bis(1,3-butadiene) metal complex, [Fe(η4-C4H 6)2]_ (see structure). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6132 / 6136

页数：5

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